Stephen K. Hashmi

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A. Stephen K. Hashmi gives the laudation for Felix R. Fischer

A. Stephen K. Hashmi (* 1963 in Munich ) is a German chemist . He is Professor of Organic Chemistry at the Ruprecht-Karls-Universität Heidelberg .

Life

Stephen Hashmi was born in Munich, after attending the Werner-Heisenberg-Gymnasium in Garching near Munich and a 15-month military service, from 1983 he studied chemistry at the Ludwig-Maximilians-Universität Munich with a diploma in 1988 and a doctorate in organic chemistry with Günter Szeimies 1991 ( transition metal catalyzed coupling and cyclization reactions on highly strained carbocyclic compounds ). From 1991 to 1993 he was a post-doctoral student with Barry Trost at Stanford University and in 1998 he completed his habilitation with Johann Mulzer , with whom he initially worked from 1993 at the Free University of Berlin , from 1995 at the Goethe University in Frankfurt am Main and briefly in 1996 the University of Vienna was. After a guest stay at the University of Tasmania in Hobart in 1999, a substitute professorship at the Philipps University of Marburg and subsequent teaching assignments at the Philipps University of Marburg and the University of Stuttgart , he became Professor of Organic Chemistry at the University of Stuttgart in 2001. He has been a professor at the University of Heidelberg since 2007 and was Dean of the Faculty of Chemistry and Geosciences there from 2010 to 2012 and Dean of the Faculty of Mathematics and Natural Sciences, from 2012 to 2013 Vice Dean of the Faculty of Chemistry and Earth Sciences and has been Vice Rector for Research and Research since 2013 Structure of the University of Heidelberg.

2000, he found both gold -catalyzed hydroarylation of allenes and alkynes as an application of gold catalysts in organic chemistry, the conversion of also furan derivatives in phenols allow the first gold-catalyzed reaction of enyne -Zyklisierungs type with Gold - Carbene intermediates. This reaction was named “Hashmi phenol synthesis” after him. Such a conversion is a prerequisite for converting the carbohydrates available in large quantities from renewable raw materials (from which furans are formed through acid treatment) into a form that enables the standard processes of the chemical industry developed in the petroleum age to be used. In 1998 Stephen Hashmi was awarded the Dr. Otto Röhm Gedächtnis-Stiftung, 2001 with the Karl-Ziegler-Scholarship, 2002 with the ORCHEM-Prize of the Society of German Chemists , 2011 with the Hector Science Prize and in 2013 accepted into the Hector Fellow Academy .

Fonts

  • A. Stephen K. Hashmi, in Inventing Reactions (Ed. Lukas J. Goossen), "Gold-Catalyzed Organic Reactions", top. Organomet. Chem. 2013, 44, 143-164.  
  • with D. Toste (Editor) Modern Gold Catalyzed Synthesis , Wiley-VCH 2012
  • with Norbert Krause (editor) Modern Allene Chemistry , Wiley-VCH 2004
  • A. Stephen K. Hashmi, "Gold-Catalyzed Organic Reactions", Chem. Rev. 2007, 107, 3180-3211.
  • with Graham Hutchings Gold Catalysis , Angewandte Chemie International Edition, Volume 45, 2006, p. 7896

Web links

Individual evidence

  1. ↑ Life data, publications and academic family tree of A. Stephen K. Hashmi at academictree.org, accessed on February 8, 2018.
  2. ↑ A. Stephen K. Hashmi, Lothar Schwarz, Ji-Hyun Choi, Tanja M. Frost ,: A New Gold-Catalyzed CC Bond Formation . In: Angew. Chem. Band 112 , 2000, pp. 2382-2385 .
  3. ↑ A. Stephen K. Hashmi, Tanja M. Frost, Jan W. Bats: Highly Selective Gold-Catalyzed Arene Synthesis . In: J. Am. Chem. Soc. tape 122 , 2000, pp. 11553-11554 .
  4. ↑ A. Stephen K. Hashmi, Matthias Rudolph, Hans-Ullrich Siehl, Masato Tanaka, Jan W. Bats, Wolfgang Frey: Gold Catalysis: Deuterated Substrates as the Key for an Experimental Insight into the Mechanism and the Selectivity of the Phenol Synthesis . In: Chem. Eur. J. Band 14 , 2008, p. 3703-3708 .
  5. ↑ Laura Nunes dos Santos Comprido, Johannes EMN Klein, Gerald Knizia, Johannes Kästner, and A. Stephen K. Hashmi: On the stabilizing effects in gold-carbene complexes . In: Angew. Chem. Band 127 , 2015, p. 10477-10481 .
  6. ^ Yunfeng Chen, Wuming Yan, Novruz G. Akhmedov, Xiaodong Shi: 1,2,3-Triazoles as a Special “X-Factor” in Promoting Hashmi Phenol Synthesis . In: Org. Lett. tape 12 , 2010, p. 344-347 .
  7. ↑ Wenjie Cao, Biao Yu: A Recyclable Polystyrene-Supported Gold (I) Catalyst . In: Adv. Synth. Catal. tape 353 , 2011, pp. 1903-1907 .
  8. Jump up ↑ Simone G. Weber, David Zahner, Frank Rominger, Bernd F. Straub: Mechanistic Investigations of a Stable, Highly Active, Extremely Sterically Shielded Molecular Gold Catalyst . In: ChemCatChem . tape 5 , 2013, p. 2330-2335 .
  9. ↑ Anal Kr. Ganai, Rima Bhardwaj, Srinivas Hotha, Sayam Sen Gupta, BLV Prasad: 'Clicking' molecular hooks on silica nanoparticles to immobilize catalytically important metal complexes: the case of gold catalyst immobilization . In: New. J. Chem. Volume 34 , 2010, p. 2662-2670 .
  10. ^ A. Stephen K. Hashmi, Michael Wölfle, J. Henrique Teles, Wolfgang Frey: Bisphenols from Furfurals by Organocatalysis and Gold Catalysis . In: Synlett . 2007, p. 1747-1752 .
  11. ↑ ORCHEM Prize | Gesellschaft Deutscher Chemiker eV Accessed February 4, 2017 .
  12. ↑ Awarding of the Hector Science Prize
  13. ^ Founding ceremony of the Hector Fellow Academy
personal data
SURNAME Hashmi, Stephen K.
ALTERNATIVE NAMES Hashmi, A. Stephen K.
BRIEF DESCRIPTION German chemist
DATE OF BIRTH 1963
PLACE OF BIRTH Munich