Thioquinox

Structural formula
General
Surname	Thioquinox
other names	S , S- quinoxaline-2,3-diyl trithiocarbonate; Quinoxaline 2,3-thiocarbonate; 1,3-dithiolo [4,5- b ] quinoxaline-2-thione ( IUPAC ) ; Eradex new; Quinothionate; Thioquinox;
Molecular formula	C 9 H 4 N 2 S 3
Brief description	odorless, brown-yellow solid
External identifiers / databases
EC number	202-272-8
ECHA InfoCard	100.002.067
PubChem	7159
Wikidata	Q15628428
properties
Molar mass	236.34 g mol −1
Physical state	firmly
density	1.68 g cm −3
Melting point	180 ° C
solubility	practically insoluble in water
safety instructions
GHS hazard labeling from Regulation (EC) No. 1272/2008 (CLP) , expanded if necessary Caution
H and P phrases	H: 302
	P: ?
Toxicological data	1800 mg kg −1 ( LD 50 , rat , oral ) ; > 3000 mg kg −1 ( LD 50 , rat , transdermal ) ;
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Thioquinox is a chemical compound from the group of trithiocarbonates and quinoxaline derivatives that was patented by Bayer in 1959. Thiochinox is used as an acaricide , it also has a weak fungicidal effect.

The active ingredient thioquinox is not on the list of active ingredients of plant protection products permitted in the EU. There is no longer any approval in Germany, Austria or Switzerland.

Extraction and presentation

Thioquinox can be obtained from phosgene and 2,3-dimercaptoquinoxaline , or from thiophosgene and quinoxaline-2,3-dithiol .

Individual evidence

↑ ^a ^b ^c Entry on Thioquinox in the Hazardous Substances Data Bank , accessed October 21, 2013.
↑ ^a ^b ^c Entry on thioquinox in the GESTIS substance database of the IFA , accessed on February 1, 2016(JavaScript required) .
↑ ^a ^b Gy. Matolcsy, M. Nádasy, V. Andriska: Pesticide Chemistry . Elsevier, 1988, p. 441 ( limited preview in Google Book search).
↑ Entry on Thioquinox in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on August 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .
^ Edward W. Lawless, Thomas L. Ferguson, Alfred F. Meiners: Guidelines for the disposal of small quantities of unused pesticides . EPA, 1975, pp. 37 ( limited preview in Google Book search).
↑ Patent US3141886 : 2,3-dimercaptoquinoxaline derivatives. Registered on December 12, 1962 , published on July 21, 1964 , applicant: Bayer AG, inventor: Gunter Unterstenhöfer, Klaus Sasse, Richard Wegler . ‌
^ Directorate-General for Health and Food Safety of the European Commission: EU pesticide database ; Entry in the national registers of plant protection products in Switzerland , Austria and Germany ; accessed on February 18, 2016.

[hsdb-1] Entry on Thioquinox in the Hazardous Substances Data Bank , accessed October 21, 2013.

[GESTIS-2] Entry on thioquinox in the GESTIS substance database of the IFA , accessed on February 1, 2016(JavaScript required) .

[gyula-3] Gy. Matolcsy, M. Nádasy, V. Andriska: Pesticide Chemistry . Elsevier, 1988, p. 441 ( limited preview in Google Book search).

[CLP_100.002.067-4] Entry on Thioquinox in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on August 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .

[5] Edward W. Lawless, Thomas L. Ferguson, Alfred F. Meiners: Guidelines for the disposal of small quantities of unused pesticides . EPA, 1975, pp. 37 ( limited preview in Google Book search).

[6] Patent US3141886 : 2,3-dimercaptoquinoxaline derivatives. Registered on December 12, 1962 , published on July 21, 1964 , applicant: Bayer AG, inventor: Gunter Unterstenhöfer, Klaus Sasse, Richard Wegler . ‌

[7] Directorate-General for Health and Food Safety of the European Commission: EU pesticide database ; Entry in the national registers of plant protection products in Switzerland , Austria and Germany ; accessed on February 18, 2016.