2,4,6-trimethylaniline

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Structural formula
Structural formula of 2,4,6-trimethylaniline
General
Surname 2,4,6-trimethylaniline
other names
  • 2-amino-1,3,5-trimethylbenzene
  • Mesidine
  • 2-aminomesitylene
  • sym. trimethylaniline
Molecular formula C 9 H 13 N
Brief description

yellow-brown liquid with a characteristic odor

External identifiers / databases
CAS number 88-05-1
EC number 201-794-3
ECHA InfoCard 100.001.632
PubChem 6913
ChemSpider 21111773
Wikidata Q4596776
properties
Molar mass 135.21 g mol −1
Physical state

liquid

density

0.96 g cm −3 (20 ° C)

Melting point

−5 ° C

boiling point

232-234 ° C

solubility

practically insoluble in water

safety instructions
GHS labeling of hazardous substances
06 - Toxic or very toxic

danger

H and P phrases H: 302 + 312-330-315-319
P: 260-280-284-305 + 351 + 338-310
Toxicological data

743 mg kg −1 ( LD 50ratoral )

As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

2,4,6-Trimethylaniline ( mesidine ) is an aromatic amine with three methyl groups  (-CH 3 ) and one amino group  (-NH 2 ) as substituents on the benzene ring . It belongs to the trimethylaniline group of substances . The common name mesidine is derived from mesitylene  ( sym. Trimethylbenzene).

history

Mesidine was described by August Wilhelm von Hofmann in 1875 .

Extraction and presentation

2,4,6-Trimethylaniline is produced by nitration of mesitylene and subsequent reduction.

use

2,4,6-Trimethylaniline is used as an intermediate in the production of anthraquinone dyes , pharmaceuticals and azo polymerization initiators .

Individual evidence

  1. a b c d e f g h Entry on 2,4,6-trimethylaniline in the GESTIS substance database of the IFA , accessed on July 23, 2016(JavaScript required) .
  2. ^ AW Hofmann : Note on mesidine . In: Reports of the German Chemical Society . tape 8 , no. 1 , January 1875, p. 61–62 , doi : 10.1002 / cber.18750080119 ( PDF ).
  3. a b entry on mesidine. In: Römpp Online . Georg Thieme Verlag, accessed on November 20, 2014.

Web links

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