4-methoxy- m- phenylenediamine

Structural formula
General
Surname	4-methoxy- m- phenylenediamine
other names	2,4-diaminophenyl methyl ether; 3-amino-4-methoxyaniline; 3-amino- p- anisidine; 2,4-diamino-1-methoxybenzene; 2,4-diaminoanisole; 4-MMPD;
Molecular formula	C 7 H 10 N 2 O
Brief description	colorless solid
External identifiers / databases
EC number	210-406-1
ECHA InfoCard	100.009.461
PubChem	11976
ChemSpider	11481
Wikidata	Q20983436
properties
Molar mass	138.17 g mol −1
Physical state	firmly
Melting point	67-68 ° C
solubility	easily soluble in water; soluble in water and ethanol (sulfate);
safety instructions
H and P phrases	H: 302-341-350-411
	P: 201-273-281-308 + 313
Toxicological data	460 mg kg −1 ( LD 50 , rat , oral )
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

4-methoxy- m -phenylenediamine , short 4-MMPD , is a chemical compound from the group of substituted Anisidine .

Extraction and presentation

4-methoxy- m- phenylenediamine was first prepared in 1913 by reducing 2,4-dinitroanisole with iron and acetic acid .

properties

4-methoxy- m- phenylenediamine is a colorless solid that is easily soluble in water. The sulfate is yellowish to purple in color.

use

4-methoxy- m- phenylenediamine and its sulfate have been used as an ingredient in hair and fur dyes. It is also used as an intermediate in the manufacture of other dyes.

Individual evidence

↑ ^a ^b ^c ^d ^e ^f ^g ^h Entry on 4-methoxy-m-phenylenediamine in the GESTIS substance database of the IFA , accessed on January 10, 2017(JavaScript required) .
↑ Entry on 2,4-diaminoanisole in the Hazardous Substances Data Bank , accessed December 29, 2016.
^ ^A ^b Barry Leonard: Eighth Annual Report on Carcinogens . DIANE Publishing, 1999, ISBN 0-7881-8396-6 , pp. 88 ( limited preview in Google Book search).
↑ Entry on 4-methoxy-m-phenylenediamine in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on December 29, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .
↑ International Agency for Research on Cancer, World Health Organization: Some Thyrotropic Agents . World Health Organization, 2001, ISBN 978-92-832-1279-9 , pp. 624 ( limited preview in Google Book search).
↑ ^a ^b Richard P. Pohanish: Sittig's Handbook of Toxic and Hazardous Chemicals and Carcinogens . William Andrew, 2011, ISBN 978-1-4377-7869-4 , pp. 872 ( limited preview in Google Book search).

[GESTIS-1] ↑ ^a ^b ^c ^d ^e ^f ^g ^h Entry on 4-methoxy-m-phenylenediamine in the GESTIS substance database of the IFA , accessed on January 10, 2017(JavaScript required) .

[HSDB-2] Entry on 2,4-diaminoanisole in the Hazardous Substances Data Bank , accessed December 29, 2016.

[Barry_Leonard-3] A ^b Barry Leonard: Eighth Annual Report on Carcinogens . DIANE Publishing, 1999, ISBN 0-7881-8396-6 , pp. 88 ( limited preview in Google Book search).

[CLP_100.009.461-4] Entry on 4-methoxy-m-phenylenediamine in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on December 29, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .

[International_Agency_for_Research_on_Cancer,_World_Health_Organization-5] International Agency for Research on Cancer, World Health Organization: Some Thyrotropic Agents . World Health Organization, 2001, ISBN 978-92-832-1279-9 , pp. 624 ( limited preview in Google Book search).

[Richard_P._Pohanish-6] Richard P. Pohanish: Sittig's Handbook of Toxic and Hazardous Chemicals and Carcinogens . William Andrew, 2011, ISBN 978-1-4377-7869-4 , pp. 872 ( limited preview in Google Book search).