Balkanite

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Balkanite
General and classification
other names

IMA 1971-009

chemical formula Cu 9 Ag 5 HgS 8
Mineral class
(and possibly department)
Sulfides and sulfosalts - sulfides with Me: S, Se, Te> 1: 1
System no. to Strunz
and to Dana
2.BD.15 ( 8th edition : II / B.09)
02.16.07.01
Crystallographic Data
Crystal system orthorhombic
Crystal class ; symbol 222, mm 2 or 2 / m 2 / m 2 / m
Space group P 222, Pmm 2 or Pmmm
Lattice parameters a  = 10.62  Å ; b  = 9.42 Å; c  = 3.92 Å Please complete the source as an individual reference!
Formula units Z  = 1 Please complete the source as an individual reference!
Twinning striped, often
Physical Properties
Mohs hardness 3.5
Density (g / cm 3 ) 6.32 g / cm
Cleavage is missing
colour steel gray, polished light gray
Line color Please complete!
transparency opaque
shine metallic

Balkanite is a rare mineral from the mineral class of sulfides and sulfosalts , more precisely the sulfides with a ratio of metal to sulfur of less than 1: 1. It crystallizes in the orthorhombic crystal system with the chemical composition Cu 9 Ag 5 HgS 8 and develops gray grains up to 3 mm in size. Rod-shaped prismatic crystals up to 0.2 mm in length have also been found on other minerals such as barite , bornite or chalcosine .

Etymology and history

Balkanite was first found 1961–1962 in the type locality , the Sedmochislenitsi mine in Wraza ( Bulgaria ). After initially mistaking it for an unknown silver mineral, Vasil Atanassov was able to determine the correct chemical composition in 1971. He named the new mineral after the Balkan mountains in which the type locality is located.

classification

Balkanit is in the classification according to Strunz to the sulphides and thio-salts having a ratio of metal to sulfur of greater than 1: counted own. 1 In the 9th edition of the system , a distinction is also made according to the cations , here balkanite is classified as a sulfide with a ratio of metal to sulfur of 1: 1 and the mercury or thallium it contains . It forms a group with Danielsit . In the 8th edition , the Balkanite group includes Danielsite, Furutobeit and Schlemait in addition to this mineral .

According to the Dana system , Hessite is one of the sulphides with different ratio formulas and forms a subgroup with Danielsite.

Education and Locations

Balkanite forms in hydrothermally at not too high temperatures. In copper deposits , it can form through displacement of bornite or tennantite . Minerals that are formed in a similar way and with which Balkanite is also associated are chalcosine and chalcopyrite . Other associated minerals include Djurleit , Digenite , Stromeyerite , Rammelsbergite , bismuth and cinnabarite .

So far, only a few sources are known. In addition to the type locality in Bulgaria, Balkanite has been found in the US state Nevada , near Leogang in Austria and on Sardinia ( Italy ).

Crystal structure

Balkanite crystallizes in the orthorhombic crystal system in the space group P222, Pmm2 or Pmmm with the lattice parameters a = 10.62 Å, b = 9.42 Å and c = 3.92 Å as well as one formula unit per unit cell .

See also

Individual evidence

  1. ^ New Dana Classification of Sulfide Minerals
  2. Mineral data sheet Balkanite (English, pdf; 63 kB)
  3. Balkanite at mindat.org

literature

  • WA Atanassow, GN Kirow: Balkanite, Cu 9 Ag 5 , HgS 8 , A New Mineral from the Sedmochislenitsi Mine, Bulgaria. In: American Mineralogist. 1973, 58, pp. 11-15 pdf .
  • Balkanit in: Anthony et al .: Handbook of Mineralogy , 1990, 1, 101 ( pdf ).

Web links