Benzil dimethyl ketal

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Structural formula
Structural formula of benzil dimethyl ketal
General
Surname Benzil dimethyl ketal
other names
  • 2,2-dimethoxy-1,2-diphenylethan-1-one
  • 2,2-dimethoxy-2-phenylacetophenone (DMPA)
Molecular formula C 16 H 16 O 3
Brief description

white odorless solid

External identifiers / databases
CAS number 24650-42-8
EC number 246-386-6
ECHA InfoCard 100.042.154
PubChem 90571
ChemSpider 81777
Wikidata Q4596747
properties
Molar mass 256.29 g mol −1
Physical state

firmly

density

1.21 g cm −3

Melting point

67-70 ° C

safety instructions
GHS labeling of hazardous substances
07 - Warning 09 - Dangerous for the environment

Caution

H and P phrases H: 317-410
P: 273-280-501
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Benzil dimethyl ketal ( DMPA , 2,2-dimethoxy-2-phenylacetophenone) is a chemical compound from the group of ketals .

Extraction and presentation

Benzil dimethyl ketal can be obtained by reacting benzil with methanol .

properties

Benzil dimethyl ketal is a white, odorless solid.

use

Benzildimethylketal is used as a photoinitiator (e.g. for 4-octyloxydiphenyliodonium hexafluoroantimonate (V) ) and hardener for lacquers and photochemical polymerisation of polyesters .

Individual evidence

  1. a b c d e f g Entry on benzil dimethyl ketal in the GESTIS substance database of the IFA , accessed on July 12, 2016(JavaScript required) .
  2. Patent CN102786404 : Preparation method for benzil dimethyl ketal. Registered on August 29, 2012 , published on July 16, 2014 , applicant: Tianjin Jiuri New Materials Co., Ltd, inventor: 吕振波, 张建锋, 张 齐, 杨天艳, 武 瑞, 白振锋, 赵国锋.
  3. Jacques Lalevee (ed.), Jean-Pierre Fouassier (ed.): Photopolymerization Initiating Systems . Royal Society of Chemistry, 2018. ISBN 1-78801330-1 , p. 37.
  4. ^ Wiley-VCH: Ullmann's Polymers and Plastics, 4 Volume Set Products and Processes . John Wiley & Sons, 2016, ISBN 978-3-527-33823-8 , pp. 785 ( limited preview in Google Book search).
  5. Data sheet 2,2-Dimethoxy-2-phenylacetophenone, 99% from Sigma-Aldrich , accessed on July 12, 2016 ( PDF ).
  6. Werner Baumann, Herberg-Liedtke: Paper chemicals data and facts on environmental protection . Springer-Verlag, 1994, ISBN 978-3-642-58040-6 , pp. 628 ( limited preview in Google Book search).