Dicrotophos

Structural formula
General
Surname	Dicrotophos
other names	O , O -dimethyl O - cis - (2-dimethylcarbamoyl-1-methylvinyl) phosphate; O , O -dimethyl N -dimethylcarbamoyl-1-methylvinyl phosphate; Phosphoric acid ( E ) -3- (dimethylamino) -1-methyl-3-oxo-1-propenyldimethyl ester; Ektafos; Bidrin; Carbicron;
Molecular formula	C 8 H 16 NO 5 P
External identifiers / databases
EC number	205-494-3
ECHA InfoCard	100.004.996
PubChem	5371560
Wikidata	Q411748
properties
Molar mass	237.19 g mol −1
Physical state	liquid
density	1.22 g cm −3
boiling point	400 ° C
Vapor pressure	9.3 h Pa (20 ° C)
solubility	miscible with acetone , ethanol , acetonitrile , chloroform , dichloromethane , xylene and water
safety instructions
H and P phrases	H: 300 + 310 + 330-410
	P: 260-264-273-280-284-301 + 310
MAK	Switzerland: 0.25 mg m −3
Toxicological data	~ 22 mg kg −1 ( LD 50 , rat , oral )
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Dicrotophos is a chemical compound from the group of carboxamides and phosphoric acid esters that is used as an insecticide .

properties

Dicrotophos in technical form is a yellow-brown liquid with a mild ester-like odor that contains more than 85% dicrotophos. From a temperature of 25 - 30 ° C it begins to decompose.

use

Dicrotophos, introduced in 1956, is used as an insecticide like its metabolite Monocrotophos . Its ( E ) -isomer has a stronger effect than the ( Z ) -isomer as a cholinesterase inhibitor, which is why the majority of the industrially produced dicrotophos consists of the ( E ) -isomer.

Admission

Dicrotophos has not been included in the list of active ingredients in plant protection products approved in Europe . There is consequently no approval of a plant protection product containing dicrotophos in Germany and Austria, and no such product is approved in Switzerland either.

safety instructions

Dicrotophos is highly toxic, especially for bees and birds.

Web links

dicrotophos (Bidrin) Chemical Profile 4/85

Individual evidence

↑ ^a ^b ^c ^d ^e ^f Entry on Dicrotophos in the GESTIS substance database of the IFA , accessed on February 1, 2016(JavaScript required) .
↑ ^a ^b ^c ^d EXTOXNET: Dicrotophos , accessed December 6, 2016.
↑ Entry on (E) -3- (dimethylamino) -1-methyl-3-oxoprop-1-enyl dimethyl phosphate in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on February 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .
↑ Swiss Accident Insurance Fund (Suva): Limit values - current MAK and BAT values (search for 141-66-2 or Dicrotophos ), accessed on November 2, 2015.
↑ CDC: Dicrotophos (PDF file; 346 kB).
↑ Regulation (EC) No. 2076/2002 (PDF) of the Commission of November 20, 2002.
↑ General Directorate Health and Food Safety of the European Commission: Entry on Dicrotophos in the EU pesticide database; Entry in the national registers of plant protection products in Switzerland , Austria and Germany ; Retrieved March 3, 2016.

[GESTIS-1] ↑ ^a ^b ^c ^d ^e ^f Entry on Dicrotophos in the GESTIS substance database of the IFA , accessed on February 1, 2016(JavaScript required) .

[extonet-2] EXTOXNET: Dicrotophos , accessed December 6, 2016.

[CLP_100.004.996-3] Entry on (E) -3- (dimethylamino) -1-methyl-3-oxoprop-1-enyl dimethyl phosphate in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on February 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .

[4] Swiss Accident Insurance Fund (Suva): Limit values - current MAK and BAT values (search for 141-66-2 or Dicrotophos ), accessed on November 2, 2015.

[5] CDC: Dicrotophos (PDF file; 346 kB).

[6] Regulation (EC) No. 2076/2002 (PDF) of the Commission of November 20, 2002.

[PSM-7] General Directorate Health and Food Safety of the European Commission: Entry on Dicrotophos in the EU pesticide database; Entry in the national registers of plant protection products in Switzerland , Austria and Germany ; Retrieved March 3, 2016.