Di- n -propyl ether

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Structural formula
Structure of dipropyl ether
General
Surname Dipropyl ether
other names
  • 1-propoxypropane ( IUPAC )
  • Dipropyl ether
  • Dipropyloxide
  • n- propyl ether
  • 1,1'-oxybispropane
Molecular formula C 6 H 14 O
Brief description

colorless liquid

External identifiers / databases
CAS number 111-43-3
EC number 203-869-6
ECHA InfoCard 100.003.518
PubChem 8114
Wikidata Q414772
properties
Molar mass 102.17 g mol −1
Physical state

liquid

density

0.75 g cm −3 (20 ° C)

Melting point

−122 ° C

boiling point

90 ° C

Vapor pressure

73 hPa (20 ° C)

solubility

poor in water (3.8 g l −1 at 25 ° C)

Refractive index

1.3809 (20 ° C)

safety instructions
GHS hazard labeling from  Regulation (EC) No. 1272/2008 (CLP) , expanded if necessary
02 - Highly / extremely flammable 07 - Warning

danger

H and P phrases H: 225-336
EUH: 019-066
P: 210-370 + 378-403 + 235
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

The di- n- propyl ether (sometimes only dipropyl ether ) is a representative of the class of open-chain ethers . Other representatives of these ethers are, for example, dimethyl ether and diethyl ether . Like other ethers, it is suitable as a solvent.

There are also two isomers , the diisopropyl ether and the isopropyl n -propyl ether .

Extraction and presentation

The conventional production of di- n -propyl ether in the chemical industry takes place through the etherification of n- propanol in the presence of sulfuric acid with elimination of water.

Acid-catalyzed etherification of n-propanol with sulfuric acid to di-n-propyl ether

It is an acid-catalyzed condensation reaction between two alcohol molecules .

use

Dipropylether is used in the manufacture of pharmaceutical and pyrotechnic products.

Individual evidence

  1. a b c d e f g h Entry on dipropyl ether in the GESTIS substance database of the IFA , accessed on January 8, 2020(JavaScript required) .
  2. David R. Lide (Ed.): CRC Handbook of Chemistry and Physics . 90th edition. (Internet version: 2010), CRC Press / Taylor and Francis, Boca Raton, FL, Physical Constants of Organic Compounds, pp. 3-222.
  3. Entry on Dipropyl ether in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on February 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .
  4. Michael Sakuth, Thomas Mensing, Joachim Schuler, Wilhelm Heitmann, Günther Strehlke, Dieter Mayer: Ethers, Aliphatic. In: Ullmann's Encyclopedia of Industrial Chemistry . Wiley ‐ VCH Verlag GmbH & Co. KGaA., April 15, 2010, p. 10, doi : 10.1002 / 14356007.a10_023.pub2 .