Idoses

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Structural formula
Structure of Idose
Fischer projection , open-chain representation
General
Surname D - (-) - idose, L - (+) - idose
other names
  • (2 S , 3 R , 4 S , 5 R ) -pentahydroxyhexanal
  • (2 R , 3 S , 4 R , 5 S ) -pentahydroxyhexanal
Molecular formula C 6 H 12 O 6
Brief description

colorless syrup

External identifiers / databases
CAS number
  • 5978-95-0 ( D -Idose)
  • 5934-56-5 ( L -Idose)
EC number 227-780-7
ECHA InfoCard 100.025.255
PubChem 111123
ChemSpider 99744
Wikidata Q423179
properties
Molar mass 180.16 g mol −1
Physical state

solid, technically often liquid

solubility

soluble in water

safety instructions
GHS hazard labeling
no classification available
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Idose is a monosaccharide with six carbon atoms. This sugar belongs to the group of non-naturally occurring aldohexoses .

By oxidation of the terminal CH 2 OH group on the carboxy group (-COOH) which arises iduronic acid (a uronic acid ). This is a component of the two glycosaminoglycans dermatan sulfate and heparan sulfate .

As with any sugar (except for dihydroxyacetone ) there are two isomeric forms that are mirror images of each other ( enantiomers ). Whenever “Idose” is mentioned in this text or in the scientific literature without any additional name ( prefix ), D -Idose is meant. L -Idose is of only marginal importance.

properties

In aqueous solution, an intramolecular ring closure sometimes occurs, so that an equilibrium is established between the aldehyde form and the two ring forms ( furanose and pyranose ):

D -Idose - spellings
Wedge formula Haworth notation
D-Idose Keilstrich.svg Alpha-D-Idofuranose.svg
α- D -idofuranose
16%
Beta-D-idofuranose.svg
β- D -idofuranose
16%
Alpha-D-Idopyranose.svg
α- D -idopyranose
31%
Beta-D-Idopyranose.svg
β- D -idopyranose
37%

Web links

Commons : Idose  - collection of images, videos and audio files

Individual evidence

  1. a b Entry on Idose. In: Römpp Online . Georg Thieme Verlag, accessed on December 28, 2014.
  2. This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
  3. Jürg Hunziker: Carbohydrate Chemistry ( Memento from May 10, 2008 in the Internet Archive ), April 1, 2007.