MIL-53

from Wikipedia, the free encyclopedia
Crystal structure
Structure of MIL-53
gray: Al 3+ , red: O 2− , black: C
General
Surname MIL-53
other names
  • Aluminum hydroxoterephthalate
  • Aluminum hydroxo-1,4-benzodicarboxylate
Ratio formula C 8 H 5 AlO 5
External identifiers / databases
CAS number 654061-20-8
Wikidata Q1881493
properties
Molar mass 208.10 g mol −1
Physical state

firmly

Melting point

Decomposition from 500 ° C

safety instructions
GHS hazard labeling
no classification available
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

MIL-53 (MIL ⇒ M atériaux de l ' I nstitut L avoisier ) is a well known and well studied material structure of the class of metal-organic frameworks ( MOF s). It was made by Gérard Férey's group at the Lavoisier Institute at the University of Versailles-Saint-Quentin-en-Yvelines . A distinction is made between MIL-53 as ( as = as synthesized, with inclusions of terephthalic acid ), MIL-53 lt ( lt = low temperature, the low temperature modification) and MIL-53 ht ( ht = high temperature, the high temperature modification).

Known structural analogues

The MIL-53 structure was synthesized using various metals, predominantly trivalent metals and, less commonly, bivalent or tetravalent metals.

Overview of known MIL-53 (M) structural analogs
designation Metal center and

Oxidation state

Year of first publication alternative name Citation
MIL-53 (V) V 3+ 2002 MIL-47
V 4+
MIL-53 (Cr) Cr 3+ 2002
MIL-53 (Al) Al 3+ 2004
MIL-53 (Fe) Fe 3+ 2005
Fe 2+ 2005
MIL-53 (In) In 3+ 2005
MIL-53 (Co) Co 2+ 2005 MOF-71
MIL-53 (Ga) Ga 3+ 2008
MIL-53 (Mn) Mn 2+ 2010
MIL-53 (Sc) Sc 3+ 2011
MIL-53 (Ni) Ni 2+ 2013

Not only different metals, but also different derivatives of terephthalic acid can be used as linker molecules to produce MIL-53 structures. In addition to the two carboxylate groups, these linker molecules usually have one or more additional functional groups on the benzene ring, which are not used to build up the framework structure.

Overview of MIL-53 (M) materials with functionalized linker molecules
Functional linker Metal center (M)
V Cr Al Fe In Ga
2-aminoterephthalates

2-aminobenzene-1,4-dicarboxylate

-
2-Fluorobenzene-1,4-dicarboxylate

2-fluorobenzene-1,4-dicarboxylate

- - - -
2-chlorobenzene-1,4-dicarboxylate

2-chlorobenzene-1,4-dicarboxylate

- -
2-bromobenzene-1,4-dicarboxylate

2-bromobenzene-1,4-dicarboxylate

- -
2-iodobenzene-1,4-dicarboxylate

2-iodobenzene-1,4-dicarboxylate

- - - - -
2-nitrobenzene-1,4-dicarboxylate

2-nitrobenzene-1,4-dicarboxylate

- - - -
Benzene-1,2,4-tricarboxylate

Benzene 1,2,4-tricarboxylate

- - - - -
2-methylbenzene-1,4-dicarboxylate

2-methylbenzene-1,4-dicarboxylate

- -
2-Trifluoromethylbenzene-1,4-dicarboxylate

2-trifluoromethylbenzene-1,4-dicarboxylate

- - - - -
2-Hydroxybenzene-1,4-dicarboxylate

2-hydroxybenzene-1,4-dicarboxylate

- - - -
2-methoxybenzene-1,4-dicarboxylate

2-methoxybenzene-1,4-dicarboxylate

- - - - -
2-sulfobenzene-1,4-dicarboxylate

2-sulfonic acid benzene-1,4-dicarboxylate

- - - - -
2-isocyanatebenzene-1,4-dicarboxylate

2-isocyanatobenzene-1,4-dicarboxylate

- - - - -
2-isothiocyanatebenzene-1,4-dicarboxylate

2-isothiocyanatobenzene-1,4-dicarboxylate

- - - - -
2,5-dimethylbenzene-1,4-dicarboxylate

2,5-dimethylbenzene-1,4-dicarboxylate

- - - - -
2,5-dihydroxybenzene-1,4-dicarboxylate

2,5-dihydroxybenzene-1,4-dicarboxylate

- -
2,5-dithiolbenzene-1,4-dicarboxylate

2,5-dithiolbenzene-1,4-dicarboxylate

- - - - -
2,5-fluorobenzene-1,4-dicarboxylate

2,5-difluorobenzene-1,4-dicarboxylate

- - - -
2,5-bis (trifluoromethyl) benzene-1,4-dicarboxylate

2,5-bis (trifluoromethyl) benzene-1,4-dicarboxylate

- - - -
2-Amino-5-nitrobenzene-1,4-dicarboxylate

2-amino-5-nitrobenzene-1,4-dicarboxylate

- - -
Benzene-1,2,4,5-tetracarboxylate

Benzene 1,2,4,5-tetracarboxylate

- -

MIL-121

MIL-82 - -
2,3,5,6-tetramethylbenzene-1,4-dicarboxylate

2,3,5,6-tetramethylbenzene-1,4-dicarboxylate

-

MIL-105

- - - -
2,3,5,6-tetrachlorobenzene-1,4-dicarboxylate

2,3,5,6-tetrachlorobenzene-1,4-dicarboxylate

- - - - -
2,3,5,6-Tetrabromobenzene-1,4-dicarboxylate

2,3,5,6-tetrabromobenzene-1,4-dicarboxylate

- - - - -
Naphthalenes-1,4-dicarboxylates

Naphthalene-1,4-dicarboxylate

- - - -

synthesis

MIL-53 can be obtained by a hydrothermal synthesis starting from aluminum nitrate and terephthalic acid in water in a molar ratio of 1: 0.5: 80 at 180 ° C. The as- form terephthalic acid trapped in the pores can be removed by sublimation . At 500 K, only the ht form is present.

properties

All forms of MIL-53 share the same network structure . One-dimensional parallel chains of [AlO 4 (OH) 2 ] octahedra are connected by the terephthalic linkers to form a three-dimensional network. The carboxylate groups coordinate the [Al (O 4 ) (OH) 2 ] octahedra in a bridging manner, and these are also vertically linked by the OH groups. In between there are pores up to 8.5 Å in size. When heated, MIL-53 undergoes a reversible structural change from an open-pore to a closed-pore structure. This shows a hysteresis behavior, the transition occurs when heated at 125–150 K, when cooled only at 325–375 K. The high temperature modification and MIL-53 as crystallize in the orthorhombic crystal system , while the low temperature modification is present in the monoclinic crystal system .

MIL-53 is much more chemically resistant than most other MOFs. The connection is not destroyed by air or water and is thermally stable up to 500 ° C.

MIL-53 can adsorb various gases such as carbon dioxide , water , hydrogen or methane . Due to the flexibility of the network, it can change when carbon dioxide or water is absorbed; this is referred to as a kind of "breathing".

Individual evidence

  1. ↑ a b c d e f g T. Loiseau, C. Serre, C. Huguenard, G. Fink, F. Taulelle, M. Henry, T. Bataille, G. Férey: A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL-53) Upon Hydration. In: Chem. Eur. J. 2004, 10, pp. 1373-1382, doi: 10.1002 / chem.200305413 .
  2. ↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
  3. ↑ Franck Millange, Richard I. Walton: MIL-53 and Its Analogues Isoreticular: a Review of the Chemistry and Structure of a prototypical Flexible Metal-Organic Framework . In: Israel Journal of Chemistry . tape 58 , no. 9-10 , October 2018, pp. 1019-1035 , doi : 10.1002 / ijch.201800084 ( wiley.com [accessed April 7, 2020]).
  4. ↑ Karin Barthelet, Jérôme Marrot, Didier Riou, Gérard Férey: A Breathing Hybrid Organic-Inorganic Solid with Very Large Pores and High Magnetic Characteristics . In: Angewandte Chemie International Edition . tape 41 , no. 2 , 2002, ISSN  1521-3773 , p. 281-284 , doi : 10.1002 / 1521-3773 (20020118) 41: 23.0.CO; 2-Y .
  5. ^ Hervé Leclerc, Thomas Devic, Sabine Devautour-Vinot, Philippe Bazin, Nathalie Audebrand: Influence of the Oxidation State of the Metal Center on the Flexibility and Adsorption Properties of a Porous Metal Organic Framework: MIL-47 (V) . In: Journal of Physical Chemistry C . tape 115 , no. 40 , October 13, 2011, ISSN  1932-7447 , p. 19828-19840 , doi : 10.1021 / jp206655y .
  6. ↑ a b C. Serre, F. Millange, C. Thouvenot, M. Noguès, G. Marsolier, D. Louër, and G. Férey: Very Large Breathing Effect in the First Nanoporous Chromium (III) -Based Solids: MIL- 53 or Cr III (OH) • {O 2 C-C 6 H 4 -CO 2 } • {HO 2 C-C 6 H 4 -CO 2 H} x • H 2 O y . In: J. Am. Chem. Soc. 2002, 124, 45, pp. 13519-13526, doi: 10.1021 / ja0276974 .
  7. ↑ Franck Millange, Christian Serre, Gérard Férey: Synthesis, structure determination and properties of MIL-53as and MIL-53ht: the first Criii hybrid inorganic – organic microporous solids: Criii (OH) · {O2C – C6H4 – CO2} · {HO2C –C6H4 – CO2H} xElectronic supplementary information (ESI) available: crystal data, atomic coordinates and metrical parameters for MIL-53as and MIL-53ht. See http://www.rsc.org/suppdata/cc/b2/b201381a/ . In: Chemical Communications . No. 8 , April 11, 2002, p. 822-823 , doi : 10.1039 / b201381a .
  8. ^ A b Tabatha R. Whitfield, Xiqu Wang, Lumei Liu, Allan J. Jacobson: Metal-organic frameworks based on iron oxide octahedral chains connected by benzenedicarboxylate dianions . In: Solid State Sciences . tape 7 , no. 9 , September 2005, p. 1096-1103 , doi : 10.1016 / j.solidstatesciences.2005.03.007 .
  9. ↑ Ekaterina V. Anokhina, Marie Vougo-Zanda, Xiqu Wang, Allan J. Jacobson: In (OH) BDC 0.75BDCH 2 (BDC = benzenedicarboxylate), a Hybrid Inorganic - Organic Vernier Structure . In: Journal of the American Chemical Society . tape 127 , no. 43 , November 2005, ISSN  0002-7863 , p. 15000–15001 , doi : 10.1021 / ja055757a .
  10. ↑ Nathaniel L. Rosi, Jaheon Kim, Mohamed Eddaoudi, Banglin Chen, Michael O'Keeffe: Rod Packings and Metal - Organic Frameworks Constructed from Rod-Shaped Secondary Building Units . In: Journal of the American Chemical Society . tape 127 , no. 5 , February 2005, ISSN  0002-7863 , p. 1504–1518 , doi : 10.1021 / ja045123o .
  11. ↑ a b Alexis S. Munn, Guy J. Clarkson, Franck Millange, Yves Dumont, Richard I. Walton: M (ii) (M = Mn, Co, Ni) variants of the MIL-53-type structure with pyridine-N -oxide as a co-ligand . In: CrystEngComm . tape 15 , no. 45 , 2013, ISSN  1466-8033 , p. 9679 , doi : 10.1039 / c3ce41268g .
  12. ↑ Marie Vougo-Zanda, Jin Huang, Ekaterina Anokhina, Xiqu Wang, Allan J. Jacobson: Tossing and Turning: Guests in the Flexible frameworks of Metal (III) dicarboxylate . In: Inorganic Chemistry . tape 47 , no. 24 , December 15, 2008, ISSN  0020-1669 , p. 11535-11542 , doi : 10.1021 / ic800008f .
  13. ↑ Guohai Xu, Xiaoguang Zhang, Peng Guo, Chengling Pan, Hongjie Zhang: Mn II -based MIL-53 Analogues: Synthesis Using Neutral Bridging μ 2 -Ligands and Application in Liquid-Phase Adsorption and Separation of C6 - C8 Aromatics . In: Journal of the American Chemical Society . tape 132 , no. 11 , March 24, 2010, ISSN  0002-7863 , p. 3656-3657 , doi : 10.1021 / ja910818a .
  14. ↑ John PS Mowat, Stuart R. Miller, Alexandra MZ Slawin, Valerie R. Seymour, Sharon E. Ashbrook: Synthesis, characterization and adsorption properties of microporous scandium carboxylates with rigid and flexible frameworks . In: Microporous and Mesoporous Materials . tape 142 , no. 1 , June 2011, p. 322–333 , doi : 10.1016 / j.micromeso.2010.12.016 .
  15. ↑ Karen Leus, Sarah Couck, Matthias Vandichel, Gauthier Vanhaelewyn, Ying-Ya Liu: Synthesis, characterization and sorption properties of NH2-MIL-47 . In: Physical Chemistry Chemical Physics . tape 14 , no. 44 , 2012, ISSN  1463-9076 , p. 15562 , doi : 10.1039 / c2cp42137b .
  16. ↑ Tim Ahnfeldt, Daniel Gunzelmann, Thierry Loiseau, Dunja Hirsemann, Jürgen Senker: Synthesis and Modification of a Functionalized 3D Open-Framework Structure with MIL-53 Topology . In: Inorganic Chemistry . tape 48 , no. 7 , April 6, 2009, ISSN  0020-1669 , p. 3057-3064 , doi : 10.1021 / ic8023265 .
  17. ↑ Tim Ahnfeldt, Nathalie Guillou, Daniel Gunzelmann, Irene Margiolaki, Thierry Loiseau: [Al 4 (OH) 2 (OCH 3) 4 (H 2 N-bdc) 3] ⋅ x H 2 O: A 12-Connected Porous Metal- Organic Framework with an Unprecedented Aluminum-Containing Brick . In: Angewandte Chemie International Edition . tape 48 , no. 28 , June 29, 2009, pp. 5163-5166 , doi : 10.1002 / anie.200901409 .
  18. ↑ Sebastian Bauer, Christian Serre, Thomas Devic, Patricia Horcajada, Jérôme Marrot: High-Throughput Assisted Rationalization of the Formation of Metal Organic Frameworks in the Iron (III) Aminoterephthalate Solvothermal System . In: Inorganic Chemistry . tape 47 , no. September 17 , 2008, ISSN  0020-1669 , p. 7568-7576 , doi : 10.1021 / ic800538r .
  19. ↑ a b Pablo Serra-Crespo, Elena Gobechiya, Enrique V. Ramos Fernandez, Jana Juan-Alcaniz, Alberto Martinez-Joaristi: Interplay of Metal Node and amines Functionality in NH 2 -mil 53: Modulating Breathing Behavior through intra-framework Interactions . In: Langmuir . tape 28 , no. 35 , September 4, 2012, ISSN  0743-7463 , p. 12916-12922 , doi : 10.1021 / la302824j .
  20. ↑ Shyam Biswas, Tom Rémy, Sarah Couck, Dmytro Denysenko, Geert Rampelberg: Partially fluorinated MIL-47 and Al-MIL-53 frameworks: influence of functionalization on sorption and breathing properties . In: Physical Chemistry Chemical Physics . tape 15 , no. 10 , 2013, ISSN  1463-9076 , p. 3552 , doi : 10.1039 / c3cp44204g .
  21. ↑ Shyam Biswas, Tom Rémy, Sarah Couck, Dmytro Denysenko, Geert Rampelberg: Partially fluorinated MIL-47 and Al-MIL-53 frameworks: influence of functionalization on sorption and breathing properties . In: Physical Chemistry Chemical Physics . tape 15 , no. 10 , 2013, ISSN  1463-9076 , p. 3552 , doi : 10.1039 / c3cp44204g .
  22. ↑ a b c Shyam Biswas, Danny EP Vanpoucke, Toon Verstraelen, Matthias Vandichel, Sarah Couck: New Functionalized Metal – Organic Frameworks MIL-47-X (X = - Cl, - Br, - CH 3, - CF 3, - OH , - OCH 3): Synthesis, Characterization, and CO 2 Adsorption Properties . In: Journal of Physical Chemistry C . tape 117 , no. 44 , November 7, 2013, ISSN  1932-7447 , p. 22784-22796 , doi : 10.1021 / jp406835n .
  23. ↑ a b Pascal G. Yot, Ke Yang, Vincent Guillerm, Florence Ragon, Vladimir Dmitriev: Impact of the Metal Center and Functionalization on the Mechanical Behavior of MIL-53 Metal-Organic Frameworks: Impact of the Metal Center and Functionalization on the Mechanical Behavior of MIL-53 Metal-Organic Frameworks . In: European Journal of Inorganic Chemistry . tape 2016 , no. September 27 , 2016, p. 4424-4429 , doi : 10.1002 / ejic.201600263 .
  24. ↑ a b Shyam Biswas, Tim Ahnfeldt, Norbert Stock: New Functionalized Flexible Al-MIL-53-X (X = -Cl, -Br, -CH 3, -NO 2, - (OH) 2) Solids: Syntheses, Characterization , Sorption, and Breathing Behavior . In: Inorganic Chemistry . tape 50 , no. 19 , October 3, 2011, ISSN  0020-1669 , p. 9518-9526 , doi : 10.1021 / ic201219g .
  25. ↑ a b c d Thomas Devic, Patricia Horcajada, Christian Serre, Fabrice Salles, Guillaume Maurin: Functionalization in Flexible Porous Solids: Effects on the Pore Opening and the Host - Guest Interactions . In: Journal of the American Chemical Society . tape 132 , no. 3 , January 27, 2010, ISSN  0002-7863 , p. 1127–1136 , doi : 10.1021 / ja9092715 .
  26. ↑ Shyam Biswas, Danny EP Vanpoucke, Toon Verstraelen, Matthias Vandichel, Sarah Couck: New Functionalized Metal – Organic Frameworks MIL-47-X (X = - Cl, - Br, - CH 3, - CF 3, - OH, - OCH 3): Synthesis, Characterization, and CO 2 Adsorption Properties . In: Journal of Physical Chemistry C . tape 117 , no. 44 , November 7, 2013, ISSN  1932-7447 , p. 22784-22796 , doi : 10.1021 / jp406835n .
  27. ↑ a b c Shyam Biswas, Tim Ahnfeldt, Norbert Stock: New Functionalized Flexible Al-MIL-53-X (X = -Cl, -Br, -CH 3, -NO 2, - (OH) 2) Solids: Syntheses, Characterization, Sorption, and Breathing Behavior . In: Inorganic Chemistry . tape 50 , no. 19 , October 3, 2011, ISSN  0020-1669 , p. 9518-9526 , doi : 10.1021 / ic201219g .
  28. ↑ Thomas Devic, Patricia Horcajada, Christian Serre, Fabrice Salles, Guillaume Maurin: Functionalization in Flexible Porous Solids: Effects on the pore opening and the Host - Guest Interactions . In: Journal of the American Chemical Society . tape 132 , no. 3 , January 27, 2010, ISSN  0002-7863 , p. 1127–1136 , doi : 10.1021 / ja9092715 .
  29. ↑ a b c Lei Wu, Gérald Chaplais, Ming Xue, Shilun Qiu, Joël Patarin: New functionalized MIL-53 (In) solids: syntheses, characterization, sorption, and structural flexibility . In: RSC Advances . tape 9 , no. 4 , 2019, ISSN  2046-2069 , p. 1918-1928 , doi : 10.1039 / C8RA08522F .
  30. ↑ Babak Tahmouresilerd, Patrick J. Larson, Daniel K. Unruh, Anthony F. Cozzolino: Make room for iodine: systematic pore tuning of multivariate metal-organic frameworks for the catalytic oxidation of hydroquinones using hypervalent iodine . In: Catalysis Science & Technology . tape 8 , no. 17 , 2018, ISSN  2044-4753 , p. 4349-4357 , doi : 10.1039 / C8CY00794B .
  31. ↑ Nele Reimer, Barbara Gil, Bartosz Marszalek, Norbert Stock: Thermal post-synthetic modification of Al-MIL-53 – COOH: systematic investigation of the decarboxylation and condensation reaction . In: CrystEngComm . tape 14 , no. 12 , 2012, ISSN  1466-8033 , p. 4119 , doi : 10.1039 / c2ce06649a .
  32. ↑ a b Shyam Biswas, Danny EP Vanpoucke, Toon Verstraelen, Matthias Vandichel, Sarah Couck: New Functionalized Metal – Organic Frameworks MIL-47-X (X = - Cl, - Br, - CH 3, - CF 3, - OH, - OCH 3): Synthesis, Characterization, and CO 2 Adsorption Properties . In: Journal of Physical Chemistry C . tape 117 , no. 44 , November 7, 2013, ISSN  1932-7447 , p. 22784-22796 , doi : 10.1021 / jp406835n .
  33. ↑ Dieter Himsl, Dirk Wallacher, Martin Hartmann: Improving the Hydrogen-Adsorption Properties of a Hydroxy-Modified MIL-53 (Al) Structural Analogue by Lithium Doping . In: Angewandte Chemie International Edition . tape 48 , no. 25 , June 8, 2009, pp. 4639-4642 , doi : 10.1002 / anie.200806203 .
  34. ↑ Jinzhu Chen, Kegui Li, Limin Chen, Ruliang Liu, Xing Huang: Conversion of fructose into 5-hydroxymethylfurfural catalyzed by recyclable sulfonic acid-functionalized metal – organic frameworks . In: Green Chem. Band 16 , no. 5 , 2014, ISSN  1463-9262 , p. 2490-2499 , doi : 10.1039 / C3GC42414F .
  35. ↑ a b Christophe Volkringer, Seth M. Cohen: Generating Reactive MILs: Isocyanate- and Isothiocyanate-Bearing MILs through Postsynthetic Modification . In: Angewandte Chemie International Edition . tape 49 , no. 27 , June 21, 2010, p. 4644–4648 , doi : 10.1002 / anie.201001527 .
  36. ^ A b c Andrea Centrone, Takuya Harada, Scott Speakman, T. Alan Hatton: Facile Synthesis of Vanadium Metal-Organic Frameworks and their Magnetic Properties . In: Small . tape 6 , no. 15 , July 7, 2010, p. 1598-1602 , doi : 10.1002 / smll.201000773 .
  37. ↑ Andrea Centrone, Takuya Harada, Scott Speakman, T. Alan Hatton: Facile Synthesis of Vanadium Metal-Organic Frameworks and their Magnetic Properties . In: Small . tape 6 , no. 15 , July 7, 2010, p. 1598-1602 , doi : 10.1002 / smll.201000773 .
  38. ↑ Alexis S. Munn, Franck Millange, Michel Frigoli, Nathalie Guillou, Clément Falaise: Iodine sequestration by thiol-modified MIL-53 (A1) . In: CrystEngComm . tape 18 , no. 41 , 2016, ISSN  1466-8033 , p. 8108-8114 , doi : 10.1039 / C6CE01842D .
  39. ↑ Shyam Biswas, Sarah Couck, Dmytro Denysenko, Asamanjoy Bhunia, Maciej Grzywa: Sorption and breathing properties of difluorinated MIL-47 and Al-MIL-53 frameworks . In: Microporous and Mesoporous Materials . tape 181 , November 2013, p. 175-181 , doi : 10.1016 / j.micromeso.2013.07.030 .
  40. ↑ Shyam Biswas, Sarah Couck, Dmytro Denysenko, Asamanjoy Bhunia, Maciej Grzywa: Sorption and breathing properties of difluorinated MIL-47 and Al-MIL-53 frameworks . In: Microporous and Mesoporous Materials . tape 181 , November 2013, p. 175-181 , doi : 10.1016 / j.micromeso.2013.07.030 .
  41. ↑ Claudia Zlotea, Delphine Phanon, Matjaz Mazaj, Daniela Heurtaux, Vincent Guillerm: Effect of NH2 and CF3 functionalization on the hydrogen sorption properties of MOFs . In: Dalton Transactions . tape 40 , no. 18 , 2011, ISSN  1477-9226 , p. 4879 , doi : 10.1039 / c1dt10115c .
  42. ↑ a b c Karen Markey, Martin Krüger, Tomasz Seidler, Helge Reinsch, Thierry Verbiest: Emergence of Nonlinear Optical Activity by Incorporation of a Linker Carrying the p -Nitroaniline Motif in MIL-53 Frameworks . In: Journal of Physical Chemistry C . tape 121 , no. 45 , November 16, 2017, ISSN  1932-7447 , p. 25509-25519 , doi : 10.1021 / acs.jpcc.7b09190 , PMID 29170688 , PMC 5694968 (free full text).
  43. ↑ Christophe Volkringer, Thierry Loiseau, Nathalie Guillou, Gérard Férey, Mohamed Haouas: High-Throughput Aided Synthesis of the Porous Metal - Organic Framework-Type Aluminum Pyromellitate, MIL-121, with Extra Carboxylic Acid Functionalization . In: Inorganic Chemistry . tape 49 , no. November 21 , 2010, ISSN  0020-1669 , p. 9852-9862 , doi : 10.1021 / ic101128w .
  44. ↑ Morgane Sanselme, Jean-Marc Grenèche, Myriam Riou-Cavellec, Gérard Férey: The first ferric carboxylate with a three-dimensional hydrid open-framework (MIL-82): its synthesis, structure, magnetic behavior and study of its dehydration by Mössbauer spectroscopy . In: Solid State Sciences . tape 6 , no. 8 , August 2004, p. 853-858 , doi : 10.1016 / j.solidstatesciences.2004.04.001 .
  45. ↑ Christian Serre, Franck Millange, Thomas Devic, Nathalie Audebrand, Wouter Van Beek: Synthesis and structure determination of new open-framework chromium carboxylate MIL-105 or CrIII (OH) · {O2C – C6 (CH3) 4 – CO2} · nH2O . In: Materials Research Bulletin . tape 41 , no. 8 , August 2006, p. 1550–1557 , doi : 10.1016 / j.materresbull.2006.01.013 .
  46. ↑ Andrea Centrone, Takuya Harada, Scott Speakman, T. Alan Hatton: Facile Synthesis of Vanadium Metal-Organic Frameworks and their Magnetic Properties . In: Small . tape 6 , no. 15 , July 7, 2010, p. 1598-1602 , doi : 10.1002 / smll.201000773 .
  47. ↑ Angiolina Comotti, Silvia Bracco, Piero Sozzani, Satoshi Horike, Ryotaro Matsuda: Nanochannels of Two Distinct Cross-Sections in a Porous Al-Based Coordination Polymer . In: Journal of the American Chemical Society . tape 130 , no. 41 , October 15, 2008, ISSN  0002-7863 , p. 13664-13672 , doi : 10.1021 / ja802589u .
  48. ↑ Yun Liu, Jae-Hyuk Her, Anne Dailly, Anibal J. Ramirez-Cuesta, Dan A. Neumann, Craig M. Brown: Reversible Structural Transition in MIL-53 with Large Temperature Hysteresis. In: J. Am. Chem. Soc. 2008, 130, pp. 11813-11818, doi: 10.1021 / ja803669w .
  49. ↑ Anne Boutin, Marie-Anne Springuel-Huet, Andrei Nossov, Antoine Gédéon, Thierry Loiseau, Christophe Volkringer, Gérard Férey, François-Xavier Coudert, Alain H. Fuchs: Breathing Transitions in MIL-53 (Al) Metal-Organic Framework Upon Xenon adsorption. In: Angewandte Chemie . 2009, 121, pp. 8464-8467, doi: 10.1002 / anie.200903153 .