Sulfuryl chloride fluoride

Structural formula
	Wedges to clarify the spatial structure
General
Surname	Sulfuryl chloride fluoride
other names	Sulfuryl fluoride chloride
Molecular formula	ClFO 2 S
Brief description	colorless, pungent smelling gas
External identifiers / databases
EC number	237-126-2
ECHA InfoCard	100.033.737
PubChem	26159
Wikidata	Q3074520
properties
Molar mass	118.52 g mol −1
Physical state	gaseous
density	1.623 g cm −3 (0 ° C)
Melting point	−124.7 ° C
boiling point	7.1 ° C
safety instructions
H and P phrases	H: 301-311-331-314
	P: 261-280-301 + 310-305 + 351 + 338-310
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Sulfuryl chloride fluoride is an inorganic chemical compound from the group of acid chlorides and acid fluorides .

Extraction and presentation

Sulfuryl chloride fluoride can be obtained by reacting sulfuryl chloride with antimony (III) fluoride and antimony (V) chloride as a catalyst at 300 ° C. and overpressure.

{\ displaystyle \ mathrm {3 \ SO_ {2} Cl_ {2} + SbF_ {3} \ longrightarrow 3 \ SO_ {2} ClF + SbCl_ {3}}}

It is also possible to display it by reacting sulfuryl chloride with sodium fluoride at 80 ° C.

{\ displaystyle \ mathrm {SO_ {2} Cl_ {2} + NaF \ longrightarrow SO_ {2} ClF + NaCl}}

properties

Sulfuryl chloride fluoride is a colorless, pungent smelling gas. It does not smoke in air and reacts quickly with water and alkali lye. It does not attack glass, mercury and brass .

use

Sulfuryl chloride fluoride is used in the manufacture of novel fluorinated alkanesulfonyloxaziridines and in the alkoxylation of fullerenes . It is also used as a solvent.

Individual evidence

↑ ^a ^b ^c Georg Brauer (ed.), With the collaboration of Marianne Baudler a . a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6 , p. 191.
↑ ^a ^b ^c ^d ^e data sheet Sulfuryl chloride fluoride, technical grade, ≥90% from Sigma-Aldrich , accessed on September 20, 2013 ( PDF ).
^ ^A ^b ^c Richard J. Lewis, Sr .: Hazardous Chemicals Desk Reference . John Wiley & Sons, 2008, ISBN 0-470-33445-2 , pp. 1295 ( limited preview in Google Book search).
↑ Jeffrey W. Schubert: The Structure of Bromonium, Chloronium, and Oxonium Ions . ProQuest, 2008, ISBN 0-549-46764-5 , pp. 22 ( limited preview in Google Book search).

[brauer-1] Georg Brauer (ed.), With the collaboration of Marianne Baudler a . a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6 , p. 191.

[Sigma-2] ↑ ^a ^b ^c ^d ^e data sheet Sulfuryl chloride fluoride, technical grade, ≥90% from Sigma-Aldrich , accessed on September 20, 2013 ( PDF ).

[Richard_J._Lewis,_Sr.-3] A ^b ^c Richard J. Lewis, Sr .: Hazardous Chemicals Desk Reference . John Wiley & Sons, 2008, ISBN 0-470-33445-2 , pp. 1295 ( limited preview in Google Book search).

[Jeffrey_W._Schubert-4] Jeffrey W. Schubert: The Structure of Bromonium, Chloronium, and Oxonium Ions . ProQuest, 2008, ISBN 0-549-46764-5 , pp. 22 ( limited preview in Google Book search).