1-dodecene

Structural formula
General
Surname	1-dodecene
other names	Dodec-1-en Dodecylene Tetrapropene Tetrapropylene
Molecular formula	C 12 H 24
Brief description	colorless liquid with a benzene-like odor
External identifiers / databases
CAS number 112-41-4 EC number 203-968-4 ECHA InfoCard 100.003.608 PubChem 8183 Wikidata Q161620
properties
Molar mass	168.32 g mol −1
Physical state	liquid
density	0.76 g cm −3
Melting point	−32 ° C
boiling point	213 ° C
Vapor pressure	3.05 mbar (50 ° C)
solubility	practically insoluble in water
Refractive index	1.4294 (at 20 ° C, 589 nm)
safety instructions
GHS labeling of hazardous substances danger H and P phrases H: 304 EUH: 066 P: 301 + 310-331
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

1-Dodecene is a chemical compound from the group of aliphatic unsaturated hydrocarbons .

Occurrence

1-Dodecene occurs as a by-product in the petroleum industry during cracking and pyrolysis .

Extraction and presentation

1-Dodecene can be obtained by a Ziegler process from ethylene with triethylaluminum as a catalyst .

properties

1-Dodecene is a colorless liquid with a benzene-like odor, which is practically insoluble in water.

safety instructions

The vapors of 1-dodecene can form an explosive mixture with air ( flash point 76 ° C, ignition temperature 225 ° C).

use

By reaction with hydrogen sulfide can tert -Dodecanthiol be prepared.

Individual evidence

1. ↑ ^{a b c d e f g h i j} Entry on 1-dodecene in the GESTIS substance database of the IFA , accessed on January 8, 2018(JavaScript required) .
2. ↑ Data sheet 1-dodecene (PDF) from Merck , accessed on October 19, 2011.
3. ↑ OECD : Screening Information Dataset (SIDS) Initial Assessment Report (SIAR) for 1-dodecene , accessed on November 6, 2014.
4. ↑ Data sheet tert-dodecyl mercaptan, technical, ≥97.0% (RT) from Sigma-Aldrich , accessed on September 18, 2011 ( PDF ).