Thiazyl fluoride

Structural formula
General
Surname	Thiazyl fluoride
Molecular formula	FNS
Brief description	pungent-smelling, colorless gas
External identifiers / databases
PubChem	140430
Wikidata	Q246405
properties
Molar mass	65.07 g mol −1
Physical state	gaseous
Melting point	−89 ° C
boiling point	0.4 ° C
solubility	Decomposes in water
safety instructions
GHS hazard labeling ; no classification available
GHS hazard labeling ; no classification available
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Thiazyl fluoride is an inorganic chemical compound from the group of fluorides .

Extraction and presentation

Thiazyl fluoride can be obtained by reacting nitrogen trifluoride with sulfur at 400 ° C, whereby thiothionyl fluoride is also formed.

{\ displaystyle \ mathrm {NF_ {3} +3 \ S \ longrightarrow NSF + S_ {2} F_ {2}}}

It can also be achieved by fluorination of tetrasulfur tetranitride with iodine pentafluoride , sulfur tetrafluoride , selenium hexafluoride , cobalt (III) fluoride , etc., by thermolysis of the mercury compound Hg (NSF ₂ ) ₂

{\ displaystyle \ mathrm {Hg (NSF_ {2}) _ {2} \ longrightarrow 2 \ NSF + HgF_ {2}}}

or obtained by ammonolysis of sulfur tetrafluoride.

{\ displaystyle \ mathrm {SF_ {4} +4 \ NH_ {3} \ longrightarrow NSF + 3 \ NH_ {4} F}}

properties

Bond lengths and angles of thiazyl fluoride

Thiazyl fluoride is a pungent, colorless gas. It is not thermally stable, very reactive and decomposes on contact with water. It slowly attacks glass even at room temperature. In the liquid phase it trimerizes to (NSF) ₃ .

Individual evidence

↑ ^a ^b ^c ^d ^e ^f ^g Georg Brauer (Ed.), With the collaboration of Marianne Baudler u. a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6 , p. 205.
↑ This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.
^ ^A ^b A. F. Holleman , E. Wiberg , N. Wiberg : Textbook of Inorganic Chemistry . 101st edition. Walter de Gruyter, Berlin 1995, ISBN 3-11-012641-9 , p. 609.
^ A. Earnshaw, Norman Greenwood: Chemistry of the Elements . Elsevier, 1997, ISBN 0-08-050109-5 , pp. 736 ( limited preview in Google Book search).

[brauer-1] ↑ ^a ^b ^c ^d ^e ^f ^g Georg Brauer (Ed.), With the collaboration of Marianne Baudler u. a .: Handbook of Preparative Inorganic Chemistry. 3rd, revised edition. Volume I, Ferdinand Enke, Stuttgart 1975, ISBN 3-432-02328-6 , p. 205.

[NV-2] This substance has either not yet been classified with regard to its hazardousness or a reliable and citable source has not yet been found.

[HoWi-3] A ^b A. F. Holleman , E. Wiberg , N. Wiberg : Textbook of Inorganic Chemistry . 101st edition. Walter de Gruyter, Berlin 1995, ISBN 3-11-012641-9 , p. 609.

[A._Earnshaw,_Norman_Greenwood-4] A. Earnshaw, Norman Greenwood: Chemistry of the Elements . Elsevier, 1997, ISBN 0-08-050109-5 , pp. 736 ( limited preview in Google Book search).