Triallylamine

Structural formula
General
Surname	Triallylamine
other names	N , N , N -Tris (prop-2-en-1-yl) amine
Molecular formula	C 9 H 15 N
Brief description	colorless liquid with an amine-like odor
External identifiers / databases
CAS number 102-70-5 EC number 203-048-2 ECHA InfoCard 100.002.772 PubChem 7617 ChemSpider 7335 Wikidata Q23779745
properties
Molar mass	137.22 g mol −1
Physical state	liquid
density	0.81 g cm −3
Melting point	<−70 ° C
boiling point	approx. 151 ° C
Vapor pressure	5.33 hPa (20 ° C)
solubility	sparingly soluble in water (2.5 g l −1 at 20 ° C)
Refractive index	1.451 (20 ° C)
safety instructions
GHS labeling of hazardous substances danger H and P phrases H: 226-302-311-331-314-335 P: 210-280-301 + 330 + 331-303 + 361 + 353-304 + 340 + 311-305 + 351 + 338
Toxicological data	1030 mg kg −1 ( LD 50 ,  rat ,  oral ) 323 mg kg −1 ( LD 50 ,  rabbit ,  transdermal )
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

Triallylamine is a chemical compound from the group of aliphatic amines .

Extraction and presentation

Triallylamine 2 can be obtained by reacting allyl chloride 1 with ammonia at temperatures around 100 ° C.

In addition, the homologous compounds allylamine and diallylamine are formed .

properties

Triallylamine is a flammable, colorless liquid with an amine-like odor that is sparingly soluble in water. Its aqueous solution has an alkaline reaction.

use

Triallylamine is used to make other chemicals. It can be used, for example, in the crosslinking of highly absorbent materials and the intermediate products for the production of ion exchange resins. It can also be used in the production of polyester activators and the evocation agent for butadiene polymerization.

safety instructions

The vapors of triallylamine can form an explosive mixture with air ( flash point 31 ° C).

Individual evidence

1. ↑ ^{a b c d e f g h i j k l} Entry on triallylamine in the GESTIS substance database of the IFA , accessed on January 24, 2020(JavaScript required) .
2. ↑ ^{a b} Data sheet triallylamine from Sigma-Aldrich , accessed on January 24, 2020 ( PDF ).
3. ↑ ^{a b} Ludger Krähling, Jürgen Krey, Gerald Jacobson, Johann Grolig, Leopold Miksche: Ullmann's Fine Chemicals Vol. 1 . Wiley ‐ VCH Verlag GmbH & Co. KGaA, 2004, ISBN 978-3-527-33477-3 , p. 113 ( limited preview in Google Book search).
4. ↑ Data sheet Triallylamine, 97% at AlfaAesar, accessed on November 23, 2018 ( PDF )(JavaScript required) .