Vernolate

Structural formula
General
Surname	Vernolate
other names	S -propyl- N , N -dipropylthiocarbamate; Vernam;
Molecular formula	C 10 H 21 NOS
Brief description	colorless liquid
External identifiers / databases
EC number	217-681-7
ECHA InfoCard	100.016.075
PubChem	16003
Wikidata	Q3555984
properties
Molar mass	203.34 g mol −1
Physical state	liquid
density	0.95 g cm −3 (20 ° C)
boiling point	150 ° C (3 kPa)
Vapor pressure	1.39 Pa (25 ° C)
solubility	practically insoluble in water (0.09 g l −1 at 20 ° C)
safety instructions
H and P phrases	H: 302-411
	P: 273
Toxicological data	1780 mg kg −1 ( LD 50 , rat , oral )
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Vernolate is a chemical compound from the group of thiocarbamates .

Extraction and presentation

Vernolate can be obtained by reacting phosgene with 1-propanethiol and its product with dipropylamine .

use

Estimated application rate in the USA in 1992

Is vernolate as a selective preemergence - herbicide used in peanut, tobacco and soybeans. The compound was introduced in 1954 as by Stauffer Chemical . The amount applied fell continuously in the USA.

Admission

The active ingredient is not approved for use in plant protection products in the European Union or Switzerland .

Individual evidence

↑ ^a ^b ^c ^d Entry on Vernolat. In: Römpp Online . Georg Thieme Verlag, accessed on March 8, 2014.
↑ ^a ^b ^c ^d Entry on S-Propyldipropylthiocarbamate in the GESTIS substance database of the IFA , accessed on February 9, 2017(JavaScript required) .
↑ Vernolat data sheet from Sigma-Aldrich , accessed on May 22, 2017 ( PDF ).

↑ Entry on S-propyl dipropylthiocarbamate in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on August 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .

↑ Thomas A. Unger: Pesticide Synthesis Handbook . William Andrew, 1996, ISBN 0-8155-1853-6 , pp. 121 ( limited preview in Google Book search).

^ Directorate-General for Health and Food Safety of the European Commission: Entry on Vernolate in the EU pesticide database; Entry in the national registers of plant protection products in Switzerland , Austria and Germany ; accessed on March 26, 2016.

↑ Regulation (EC) No. 2076/2002 of the Commission of November 20, 2002 (PDF) extending the deadline according to Article 8 (2) of Council Directive 91/414 / EEC and on the non-inclusion of certain active substances in Annex I of this Directive and the revocation of the approval of plant protection products with these active substances.

[roempp-1] Entry on Vernolat. In: Römpp Online . Georg Thieme Verlag, accessed on March 8, 2014.

[GESTIS-2] Entry on S-Propyldipropylthiocarbamate in the GESTIS substance database of the IFA , accessed on February 9, 2017(JavaScript required) .

[Sigma-3] Vernolat data sheet from Sigma-Aldrich , accessed on May 22, 2017 ( PDF ).

[CLP_100.016.075-4] Entry on S-propyl dipropylthiocarbamate in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on August 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .

[unger-5] Thomas A. Unger: Pesticide Synthesis Handbook . William Andrew, 1996, ISBN 0-8155-1853-6 , pp. 121 ( limited preview in Google Book search).

[6] Directorate-General for Health and Food Safety of the European Commission: Entry on Vernolate in the EU pesticide database; Entry in the national registers of plant protection products in Switzerland , Austria and Germany ; accessed on March 26, 2016.

[7] Regulation (EC) No. 2076/2002 of the Commission of November 20, 2002 (PDF) extending the deadline according to Article 8 (2) of Council Directive 91/414 / EEC and on the non-inclusion of certain active substances in Annex I of this Directive and the revocation of the approval of plant protection products with these active substances.