Zinc acetylacetonate

Structural formula
General
Surname	Zinc acetylacetonate
other names	Bis (acetylacetonato) zinc (II); Bis (2,4-pentanedionato) zinc (II); Zinc (II) acetylacetonate; Zn (acac) 2 ;
Molecular formula	C 10 H 14 O 4 Zn
Brief description	crystalline solid
External identifiers / databases
EC number	237-860-3
ECHA InfoCard	100.034.405
PubChem	5360437
ChemSpider	4514507
Wikidata	Q27270278
properties
Molar mass	263.61 g / mol g mol −1
Physical state	firmly
density	1.41 g cm −3
Melting point	124-126 ° C
boiling point	129-131 ° C (13 hPa)
Vapor pressure	1 hPa (20 ° C)
solubility	slightly soluble in water (6.9 g / l); soluble in most organic solvents;
safety instructions
GHS labeling of hazardous substances Caution
H and P phrases	H: 319
	P: 305 + 351 + 338
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Zinc acetylacetonate is a chemical compound from the group of acetylacetonates .

Extraction and presentation

Zinc acetylacetonate can be obtained by reacting zinc sulfate with acetylacetone and sodium hydroxide .

properties

Zinc acetylacetonate is a crystalline solid that is sparingly soluble in water. The monomer which has the monoclinic space group C 2 / c (space group no. 15) can be crystallized by sublimation . The trimer with the monoclinic space group C 2 (space group no. 5) was also obtained by sublimation . Crystal structures of the monohydrate and dihydrate are also known. Template: room group / 15 Template: room group / 5

use

Zinc acetylacetonate is used as a hydrate for the production of magnetic (Zn, Fe) Fe ₂ O ₄ films, zinc oxide and as a catalyst in organic chemistry.

Individual evidence

↑ ^a ^b ^c ^d ^e ^f ^g ^h ⁱ Data sheet Zinc (II) acetylacetonate, Zinc (II) acetylacetonate for synthesis from Sigma-Aldrich , accessed on May 12, 2019 ( PDF ).
↑ ^a ^b M. J. Bennett, FA Cotton, R. Eiss: The crystal and molecular structure of trimeric bis (acetylacetonato) zinc (II). In: Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 24, 1968, p. 904, doi : 10.1107 / S0567740868003390 .
↑ ^a ^b ^c S. Barta, Nancy & Stille, John. (2001). e-EROS Encyclopedia of Reagents for Organic Synthesis. doi : 10.1002 / 047084289X.rb097 .
^ W. Clegg: Private Communication . In: CSD Communication . 2016, doi : 10.5517 / ccdc.csd.cc1mcf4k .
↑ H. Montgomery, EC Lingafelter: The crystal structure of monoaquobisacetylacetonatozinc . In: Acta Crystallographica . tape 16 , no. 8 , 1963, pp. 748-752 , doi : 10.1107 / S0365110X6300195X .
↑ P. Harbach, H.-W. Lerner, M. Bolte: Diaquadiacetylacetonatozinc (II) . In: Acta Crystallographica Section E . tape 59 , no. 9 , 2003, p. m724-m725 , doi : 10.1107 / S1600536803015848 .
↑ Data sheet Zinc acetylacetonate hydrate, 99.995% trace metals basis from Sigma-Aldrich , accessed on May 13, 2019 ( PDF ).
↑ Yoichi Inubushi, Ryoji Takami et al. a .: Mechanism of Formation of Nanocrystalline ZnO Particles through the Reaction of Zn (acac) ₂ with NaOH in EtOH. In: Journal of Colloid and Interface Science. 200, 1998, p. 220, doi : 10.1006 / jcis.1997.5354 .

[Sigma-1] ↑ ^a ^b ^c ^d ^e ^f ^g ^h ⁱ Data sheet Zinc (II) acetylacetonate, Zinc (II) acetylacetonate for synthesis from Sigma-Aldrich , accessed on May 12, 2019 ( PDF ).

[DOI10.1107/S0567740868003390-2] M. J. Bennett, FA Cotton, R. Eiss: The crystal and molecular structure of trimeric bis (acetylacetonato) zinc (II). In: Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 24, 1968, p. 904, doi : 10.1107 / S0567740868003390 .

[Barta-3] S. Barta, Nancy & Stille, John. (2001). e-EROS Encyclopedia of Reagents for Organic Synthesis. doi : 10.1002 / 047084289X.rb097 .

[4] W. Clegg: Private Communication . In: CSD Communication . 2016, doi : 10.5517 / ccdc.csd.cc1mcf4k .

[5] H. Montgomery, EC Lingafelter: The crystal structure of monoaquobisacetylacetonatozinc . In: Acta Crystallographica . tape 16 , no. 8 , 1963, pp. 748-752 , doi : 10.1107 / S0365110X6300195X .

[6] P. Harbach, H.-W. Lerner, M. Bolte: Diaquadiacetylacetonatozinc (II) . In: Acta Crystallographica Section E . tape 59 , no. 9 , 2003, p. m724-m725 , doi : 10.1107 / S1600536803015848 .

[SigmaHydrat-7] Data sheet Zinc acetylacetonate hydrate, 99.995% trace metals basis from Sigma-Aldrich , accessed on May 13, 2019 ( PDF ).

[DOI10.1006/jcis.1997.5354-8] Yoichi Inubushi, Ryoji Takami et al. a .: Mechanism of Formation of Nanocrystalline ZnO Particles through the Reaction of Zn (acac) ₂ with NaOH in EtOH. In: Journal of Colloid and Interface Science. 200, 1998, p. 220, doi : 10.1006 / jcis.1997.5354 .