4,4'-oxydianiline

Structural formula
General
Surname	4,4'-oxydianiline
other names	4,4'-diaminodiphenyl ether; Bis (p-aminophenyl) ether; ODA; Bis (4-aminophenyl) ether; 4,4′-DADPE; 4,4'-diaminobiphenyloxide; Oxybis (4-aminobenzene);
Molecular formula	C 12 H 12 N 2 O
Brief description	light gray odorless solid
External identifiers / databases
EC number	202-977-0
ECHA InfoCard	100.002.707
PubChem	7579
ChemSpider	7298
Wikidata	Q3704503
properties
Molar mass	200.24 g mol −1
Physical state	firmly
solubility	practically insoluble in water
safety instructions
H and P phrases	H: 301 + 311 + 331-317-340-350-361f-410
	P: 201-273-302 + 352-304 + 340-308 + 310
Authorization procedure under REACH	particularly worrying : carcinogenic, toxic for reproduction ( CMR )
Toxicological data	725 mg kg −1 ( LD 50 , rat , oral )
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

4,4'-Oxydianiline is a chemical compound from the group of ethers of aniline .

Extraction and presentation

4,4'-Oxydianiline can be obtained by reacting 4,4'-dinitrodiphenyl ether with tin and hydrochloric acid in the presence of ethanol .

properties

4,4'-Oxydianiline is a flammable, light gray, odorless solid that is practically insoluble in water. It decomposes when heated above 189–192 ° C.

use

4,4'-Oxydianiline is a flexible diamine and is used to tailor the properties of aerogels. It is widely used in the manufacture of polyimides and poly (ester-imide) s.

Individual evidence

↑ ^a ^b ^c ^d ^e ^f Entry on 4,4′-oxydianiline in the GESTIS substance database of the IFA , accessed on January 8, 2018(JavaScript required) .
↑ Entry on 4,4′-oxydianiline in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on August 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .
↑ Entry in the SVHC list of the European Chemicals Agency , accessed on October 18, 2015.
↑ ^a ^b Entry on BIS (4-AMINOPHENYL) ETHER in the Hazardous Substances Data Bank , accessed on March 1, 2015.
↑ Data sheet 4,4′-Oxydianiline, 99% from Sigma-Aldrich , accessed on March 1, 2015 ( PDF ).

[GESTIS-1] ↑ ^a ^b ^c ^d ^e ^f Entry on 4,4′-oxydianiline in the GESTIS substance database of the IFA , accessed on January 8, 2018(JavaScript required) .

[CLP_100.002.707-2] Entry on 4,4′-oxydianiline in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on August 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .

[SVHC-3] Entry in the SVHC list of the European Chemicals Agency , accessed on October 18, 2015.

[HSDB-4] Entry on BIS (4-AMINOPHENYL) ETHER in the Hazardous Substances Data Bank , accessed on March 1, 2015.

[Sigma-5] Data sheet 4,4′-Oxydianiline, 99% from Sigma-Aldrich , accessed on March 1, 2015 ( PDF ).