Diniconazole

Structural formula
	Simplified structural formula without complete stereochemistry
General
Surname	Diniconazole
other names	( E ) -β - ((dichlorophenyl) methylene) -α- (1,1-dimethyl-ethyl) -1 H -1,2,4-triazole-1-ethanol; ( E ) - ( RS ) -1- (2,4-dichlorophenyl) -4,4-dimethyl-2- (1 H -1,2,4-triazol-1-yl) pent-1-en-3- ol ( IUPAC ) ;
Molecular formula	C 15 H 17 Cl 2 N 3 O
Brief description	beige solid
External identifiers / databases
EC number	617-485-5
ECHA InfoCard	100.108.593
PubChem	91738
ChemSpider	4944979
Wikidata	Q61653395
properties
Molar mass	326.23 g mol −1
Physical state	firmly
Melting point	134-156 ° C
safety instructions
H and P phrases	H: 302-410
	P: 273-501
Toxicological data	474 mg kg −1 ( LD 50 , rat , oral ) ; > 5000 mg kg −1 ( LD 50 , rat , transdermal ) ;
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Diniconazole is a chemical compound of chlorine from the group of conazoles . The ( R ) -isomer is called Diniconazole-M .

Extraction and presentation

Diniconazole can be obtained by reacting 3,3-dimethyl-2-butanone with bromine , 1,2,4-triazole , 2,4-dichlorobenzaldehyde and sodium borohydride or lithium aluminum hydride .

properties

Diniconazole is a beige solid.

use

Diniconazole is used as a fungicide with a protective and curative effect against various pathogens, for example in cereal, fruit, vegetable and wine growing. It was developed by Sumitomo Chemical and Chevron and launched by Sumitomo in 1983.

Individual evidence

↑ ^a ^b ^c ^d ^e ^f ^g ^h Entry on diniconazole in the GESTIS substance database of the IFA , accessed on January 26, 2015(JavaScript required) .
↑ Entry on diniconazole (ISO) in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on January 5, 2020. Manufacturers or distributors can expand the harmonized classification and labeling .
↑ External identifiers or database links for Diniconazol-M : CAS number: 83657-18-5, EC number: 617-482-9, ECHA InfoCard: 100.113.138 , PubChem : 6440728 , ChemSpider : 4944979 , Wikidata : Q27157326 .
↑ Thomas A. Unger: Pesticide Synthesis Handbook . William Andrew, 1996, ISBN 978-0-8155-1853-2 , pp. 692 ( limited preview in Google Book search).
↑ Jürgen Falbe, Manfred Regitz: Römpp Lexikon Chemie, 10th edition, 1996-1999: Volume 2: Cm - G . Georg Thieme Verlag, 2014, ISBN 3-13-199971-3 , p. 993 ( limited preview in Google Book search).
↑ Richard P. Oliver, H. Geoff Hewitt: Fungicides in Crop Protection, 2nd Edition . CABI, 2014, ISBN 978-1-78064-166-9 , pp. 53 ( limited preview in Google Book search).

[GESTIS-1] ↑ ^a ^b ^c ^d ^e ^f ^g ^h Entry on diniconazole in the GESTIS substance database of the IFA , accessed on January 26, 2015(JavaScript required) .

[CLP_100.149.226-2] Entry on diniconazole (ISO) in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on January 5, 2020. Manufacturers or distributors can expand the harmonized classification and labeling .

[3] External identifiers or database links for Diniconazol-M : CAS number: 83657-18-5, EC number: 617-482-9, ECHA InfoCard: 100.113.138 , PubChem : 6440728 , ChemSpider : 4944979 , Wikidata : Q27157326 .

[Thomas_A._Unger-4] Thomas A. Unger: Pesticide Synthesis Handbook . William Andrew, 1996, ISBN 978-0-8155-1853-2 , pp. 692 ( limited preview in Google Book search).

[Jürgen_Falbe,_Manfred_Regitz-5] Jürgen Falbe, Manfred Regitz: Römpp Lexikon Chemie, 10th edition, 1996-1999: Volume 2: Cm - G . Georg Thieme Verlag, 2014, ISBN 3-13-199971-3 , p. 993 ( limited preview in Google Book search).

[Richard_P._Oliver,_H._Geoff_Hewitt-6] Richard P. Oliver, H. Geoff Hewitt: Fungicides in Crop Protection, 2nd Edition . CABI, 2014, ISBN 978-1-78064-166-9 , pp. 53 ( limited preview in Google Book search).