Diphenylsilanediol
Structural formula | ||||||||||||||||
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General | ||||||||||||||||
Surname | Diphenylsilanediol | |||||||||||||||
other names |
Dihydroxydiphenylsilane |
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Molecular formula | C 12 H 12 O 2 Si | |||||||||||||||
Brief description |
colorless and odorless monoclinic crystals |
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External identifiers / databases | ||||||||||||||||
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properties | ||||||||||||||||
Molar mass | 216.31 g mol −1 | |||||||||||||||
Physical state |
firmly |
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density |
1.25 g cm −3 |
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Melting point |
137–141 ° C (decomposition) |
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solubility |
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safety instructions | ||||||||||||||||
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As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . |
Diphenylsilanediol , Ph 2 Si (OH) 2 , is a chemical compound and one of the silanols . The molecule has a tetrahedral geometry. In the solid state, it forms hydrogen bonds .
Manufacturing
Diphenylsilanediol can be prepared from diphenyldichlorosilane by hydrolysis .
The action of phenyllithium on silica gel results in tetraphenylsilane and triphenylsilanol as well as diphenylsilanol.
use
Diphenylsilanediol can be used as an anticonvulsant . It works similarly to phenytoin .
Individual evidence
- ↑ a b c d D. J. Neal, RD Blaumanis: Diphenylsilanediol , in Anal. Chem. 1960 , 32 , 139; doi : 10.1021 / ac60157a047 .
- ↑ a b c Entry on diphenylsilanediol in the GESTIS substance database of the IFA , accessed on February 14, 2017(JavaScript required) .
- ↑ TJ Kistenmacher, M. Rossi, LK Frevel: Crystal data for diphenylsilanediol , in: J. Appl. Cryst. 1978 , 11 , 670-671; doi : 10.1107 / S002188987801420X .
- ^ A b J.K. Fawcett, N. Camerman, A. Camerman: Stereochemical basis of anticonvulsant drug action. VI. Crystal and molecular structure of diphenylsilanediol . In: Canadian Journal of Chemistry . 55 (20), 1977, pp. 3631-3635, doi : 10.1139 / v77-510 .
- ↑ G. Martin: Dibenzyl- and Diphenyl-Silicole and -silicone , in: Chem. Ber. 1912 , 45 , 403-409; doi : 10.1002 / cber.19120450159 .
- ↑ CA Burkhard: Hydrolysis of Diphenyldichlorosilane , in J. Am. Chem. Soc. 1945 , 67 , 2173-2174; doi : 10.1021 / ja01228a034 .
- ↑ Doctoral thesis: Organic derivatives of silica gel presented by Hans-Jörg Wartmann, 1958 ( pdf )
Web links
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