Edifenphos

Structural formula
General
Surname	Edifenphos
other names	Ethyl S , S -diphenyldithiophosphate; Dithiophosphoric acid O- ethyl- S , S -diphenyl ester; EDDP;
Molecular formula	C 14 H 15 O 2 PS 2
Brief description	clear yellow to light brown liquid
External identifiers / databases
EC number	241-178-1
ECHA InfoCard	100.037.420
PubChem	28292
Wikidata	Q15632710
properties
Molar mass	310.38 g mol −1
Physical state	liquid
density	1.23 g cm −3
Melting point	-25 ° C
Vapor pressure	negligibly small
solubility	practically insoluble in water (56 mg l −1 at 20 ° C)
safety instructions
H and P phrases	H: 301 + 311 + 331-317-410
	P: 261-273-280-301 + 310-311-501
Toxicological data	100 mg kg −1 ( LD 50 , rat , oral ) ; 615 mg kg −1 ( LD 50 , rabbit , transdermal ) ;
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Edifenphos is a chemical compound from the group of thiophosphoric acid esters .

Edifenphos was introduced by Bayer in 1966 as a systemic, protective and curative fungicide .

Extraction and presentation

Edifenphos can be obtained by reacting thiophenol with ethyl phosphorus dichloridate ( ethanol + phosphorus oxychloride ).

use

The active ingredient inhibits the phosphatidyl synthesis . Under the trade name Hinosan it was used against the rice blight fungus ( Pyricularia oryzae ) and Corticium sasakii in rice cultivation.

Admission

No plant protection products containing this active ingredient are permitted in the EU or Switzerland .

Individual evidence

↑ ^a ^b Entry on Edifenphos. In: Römpp Online . Georg Thieme Verlag, accessed on January 6, 2015.
↑ ^a ^b ^c ^d ^e ^f ^g ^h Entry on Edifenphos in the GESTIS substance database of the IFA , accessed on February 1, 2016(JavaScript required) .
↑ Entry on Edifenphos in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on August 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .
^ ^A ^b György Matolcsy, Miklós Nádasy, Viktor Andriska, Sándor Terényi: Pesticide chemistry . Elsevier, 1989, ISBN 978-0-444-98903-1 , pp. 306 ( limited preview in Google Book search).
↑ Thomas A. Unger: Pesticide Synthesis Handbook . William Andrew, 1996, ISBN 0-8155-1853-6 , pp. 351 ( limited preview in Google Book Search).
↑ General Directorate Health and Food Safety of the European Commission: Entry on Edifenphos in the EU pesticide database; Entry in the national registers of plant protection products in Switzerland , Austria and Germany ; accessed on March 26, 2016.

[roempp-1] Entry on Edifenphos. In: Römpp Online . Georg Thieme Verlag, accessed on January 6, 2015.

[GESTIS-2] ↑ ^a ^b ^c ^d ^e ^f ^g ^h Entry on Edifenphos in the GESTIS substance database of the IFA , accessed on February 1, 2016(JavaScript required) .

[CLP_100.037.420-3] Entry on Edifenphos in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on August 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .

[PesChem-4] A ^b György Matolcsy, Miklós Nádasy, Viktor Andriska, Sándor Terényi: Pesticide chemistry . Elsevier, 1989, ISBN 978-0-444-98903-1 , pp. 306 ( limited preview in Google Book search).

[unger-5] Thomas A. Unger: Pesticide Synthesis Handbook . William Andrew, 1996, ISBN 0-8155-1853-6 , pp. 351 ( limited preview in Google Book Search).

[6] General Directorate Health and Food Safety of the European Commission: Entry on Edifenphos in the EU pesticide database; Entry in the national registers of plant protection products in Switzerland , Austria and Germany ; accessed on March 26, 2016.