Furathiocarb

Structural formula
General
Surname	Furathiocarb
other names	2,3-dihydro-2,2-dimethyl-7-benzofuryl-2,4-dimethyl-6-oxa-5-oxo-3-thia-2,4-diazadecanoate; Deltanet;
Molecular formula	C 18 H 26 N 2 O 5 S
Brief description	beige solid
External identifiers / databases
EC number	265-974-3
ECHA InfoCard	100.059.959
PubChem	47759
ChemSpider	43456
Wikidata	Q1474820
properties
Molar mass	382.48 g mol −1
Physical state	firmly
density	1.148 g cm −3 (20 ° C)
boiling point	160 ° C at 0.013 hPa
solubility	almost insoluble in water; miscible with most organic solvents such as acetone, methanol, isopropanol, hexane and toluene;
safety instructions
H and P phrases	H: 301-330-315-317-319-334-373-410
	P: 260-273-280-301 + 310 + 330-304 + 340 + 310-342 + 311
Toxicological data	53 mg kg −1 ( LD 50 , rat , oral ) ; 2000 mg kg −1 ( LD 50 , rat , transdermal ) ;
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Furathiocarb is a chemical compound from the group of sulfenamides and carbamates .

Extraction and presentation

Furathiocarb can be obtained by reacting n -butanol with phosgene , methylamine , sulfur dichloride and carbofuran .

properties

Furathiocarb is a water-insoluble, colorless solid. As a technical active ingredient, furathiocarb can appear as a yellow oil.

use

Furathiocarb is used as an insecticide against insects living in the ground in maize, rape, sorghum , sugar beet, sunflower and vegetables. It is a cholinesterase inhibitor.

Admission

The use of furathiocarb as an active ingredient in plant protection products is not permitted in the European Union.

In Germany, Austria and Switzerland, no pesticides with this active ingredient are permitted.

Individual evidence

↑ ^a ^b ^c data sheet Furathiocarb, PESTANAL at Sigma-Aldrich , accessed on December 20, 2012 ( PDF ).
↑ ^a ^b ^c ^d ^e ^f ^g Entry on furathiocarb in the GESTIS substance database of the IFA , accessed on January 8, 2020(JavaScript required) .
↑ ^a ^b Entry on Furathiocarb in the Hazardous Substances Data Bank , accessed December 20, 2012.
↑ Entry on 2,3-dihydro-2,2-dimethyl-7-benzofuryl 2,4-dimethyl-6-oxa-5-oxo-3-thia-2,4-diazadecanoate in the Classification and Labeling Inventory of the European Chemicals Agency ( ECHA), accessed on August 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .
↑ Thomas A. Unger: Pesticide Synthesis Handbook . William Andrew, 1996, ISBN 0-8155-1853-6 , pp. 84 ( limited preview in Google Book search).
↑ Regulation (EC) No. 2076/2002 of the Commission of November 20, 2002 extending the deadline in accordance with Article 8 (2) of Council Directive 91/414 / EEC and on the non-inclusion of certain active substances in Annex I of this directive and the revocation of authorizations of pesticides with these active ingredients (PDF) .
↑ General Directorate Health and Food Safety of the European Commission: Entry on Furathiocarb in the EU pesticide database ; Entry in the national registers of plant protection products in Switzerland , Austria and Germany ; accessed on February 24, 2016.

[Sigma-1] ta sheet Furathiocarb, PESTANAL at Sigma-Aldrich , accessed on December 20, 2012 ( PDF ).

[GESTIS-2] ↑ ^a ^b ^c ^d ^e ^f ^g Entry on furathiocarb in the GESTIS substance database of the IFA , accessed on January 8, 2020(JavaScript required) .

[HSDB-3] Entry on Furathiocarb in the Hazardous Substances Data Bank , accessed December 20, 2012.

[CLP_100.059.959-4] Entry on 2,3-dihydro-2,2-dimethyl-7-benzofuryl 2,4-dimethyl-6-oxa-5-oxo-3-thia-2,4-diazadecanoate in the Classification and Labeling Inventory of the European Chemicals Agency ( ECHA), accessed on August 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .

[Thomas_A._Unger-5] Thomas A. Unger: Pesticide Synthesis Handbook . William Andrew, 1996, ISBN 0-8155-1853-6 , pp. 84 ( limited preview in Google Book search).

[6] Regulation (EC) No. 2076/2002 of the Commission of November 20, 2002 extending the deadline in accordance with Article 8 (2) of Council Directive 91/414 / EEC and on the non-inclusion of certain active substances in Annex I of this directive and the revocation of authorizations of pesticides with these active ingredients (PDF) .

[PSM-7] General Directorate Health and Food Safety of the European Commission: Entry on Furathiocarb in the EU pesticide database ; Entry in the national registers of plant protection products in Switzerland , Austria and Germany ; accessed on February 24, 2016.