Mandelin reagent
With the mandelin reagent , also known as "vanadium sulfuric acid" , after the Russian chemist KF Mandelin, a simple spot analysis is carried out to identify alkaloids and other compounds. The reagent is made up in a ratio of 0.5–1 g of ammonium metavanadate per 100–200 ml of concentrated sulfuric acid . The United States Department of Justice recommends the exact composition of 1 g to 100 ml. It is mainly used for tests for ketamine and 4-methoxyamphetamine , but must be freshly prepared for correct detection.
substance | colour |
---|---|
2C-T-7 | chestnut brown to black |
3,4-methylenedioxyamphetamine | blue black |
4-methoxyamphetamine | reddish brown |
Acetylcysteine | yellow to green to light blue |
Acetylsalicylic acid | olive green |
Ambroxol hydrochloride | light green |
Ascorbic acid | lime green to light blue |
Atropine sulfate | brown to light green |
Benzocaine | purple to brown to red |
Benzphetamine | bright yellow-green |
Bisacodyl | violet |
Chlorpromazine | dark olive |
Ciprofloxacin | red-brown |
Clotrimazole | green yellow |
Codeine | dark olive |
Dexpanthenol | no color change |
Dextroamphetamine | medium blue green |
Dextromethamphetamine | dark yellowish green |
Diclofenac sodium salt | red-brown |
Dimethoxy meth | dark olive brown |
Doxepin | strong red-brown |
Doxylamine | yellow to blue green |
Dristan | gray olive |
Exedrine | dark olive |
Fexofenadine hydrochloride | dark red-brown |
Fluoxetine hydrochloride | gray-brown |
Fluphenazine dihydrochloride | red-brown |
Glibenclamide | yellow-greenish |
Haloperidol | light green turquoise |
heroin | medium red brown |
Hydrochlorothiazide | slightly greenish |
Indomethacin | yellow-green to black |
Ketamine | dark red orange |
cocaine | dark orange yellow |
Lactulose | brown |
Mace | medium olive green |
MDMA | blue black |
Mescaline | dark yellowish brown |
Metformin | orange |
Methadone | dark grayish blue |
Methamphetamine hydrochloride | yellow-green to blue |
Methaqualone | strong orange-yellow |
Methylphenidate | bright orange-yellow |
Metoprolol tartrate | violet |
Metronidazole | lemon yellow |
Morphine monohydrate | dark gray to reddish brown |
Sodium chloride | strong orange |
Nitrofurantoin | acid green |
Noscapine | brownish red |
Omeprazole | brown purple |
opium | olive black |
Oxycodone | dark greenish yellow |
Paracetamol | medium olive |
Paramethoxymethamphetamine | reddish brown |
Pethidine hydrochloride | Red orange |
Phenazone | light green |
Phenoxymethylpenicillin | yellow to blue |
Phenprocoumon | dark red |
Pravastatin sodium salt | dark purple |
Prednisolone | Brown black |
Procaine | dark orange |
Propoxyphene | dark reddish brown |
Pyridoxal hydrochloride | violet blue |
Ramipril | very strong green |
Salicylic acid | olive brown to green |
See also
Individual evidence
- ↑ KF Mandelin: About vanadium sulfuric acid, a new reagent for alkoloids , (In: Pharm. Ztschr. F. Russl., 22, St. Petersburg, 1883, pp. 345–357), printed by E. Wienecke, 1883.
- ^ A b Charles F. Poe, DW O'Day: A study of Mandelin's test for strychnine . In: The Journal of the American Pharmaceutical Association . Volume 19, No. 12 , 1930, ISSN 0003-0465 , pp. 1292-1299 .
- ↑ a b Color Test Reagents / Kits for Preliminary Identification of Drugs of Abuse. NIJ Standard – 0604.01. National Institute of Justice, July 2000, accessed March 4, 2016 .
- ↑ Именные реактивы. xenoid.ru, accessed March 4, 2016 .
- ↑ a b c d e f g h i j k l m n o p q r s t u v w x y z aa ab ac ad ae af ag ah ai aj Peter Greulich: Script for the "Drug Analysis" internship in the 8th semester Pharmacy. July 2010, accessed March 4, 2016 .