Naled

Structural formula
	Structural formula without stereochemistry
General
Surname	Naled
other names	Dibroma; Flibol; ( RS ) - O - (1,2-dibromo-2,2-dichloroethyl) - O , O -dimethyl phosphate;
Molecular formula	C 4 H 7 Br 2 Cl 2 O 4 P
Brief description	colorless to white solid with a faint odor
External identifiers / databases
EC number	206-098-3
ECHA InfoCard	100.005.545
PubChem	4420
Wikidata	Q424822
properties
Molar mass	380.78 g mol −1
Physical state	firmly
density	1.96 g cm −3
Melting point	26.5-27.5 ° C
boiling point	110 ° C at 0.66 mbar
Vapor pressure	2 · 10 −4 mmHg (20 ° C)
solubility	practically insoluble in water; Slightly soluble in aliphatic and readily soluble in aromatic solvents;
safety instructions
H and P phrases	H: 301-312-315-319-400
	P: 273-301 + 310 + 330-302 + 352 + 312-305 + 351 + 338-337 + 313-391
MAK	DFG : 1 mg m −3 ; Switzerland: 0.1 mg m −3 (measured as inhalable dust );
Toxicological data	92 mg kg −1 ( LD 50 , rat , oral )
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Naled is a 1: 1 mixture of two stereoisomeric chemical compounds from the group of organic phosphoric acid esters . It is used as an insecticide .

properties

Naled is a colorless to white solid with a faint odor that melts even when the temperature rises slightly and is usually marketed as a low-dose spray or a high-dose solution.

use

Naled is an insecticide from the group of phosphoric acid esters, which was first registered for this purpose in 1959 under the trade name Dibrom. About a million pounds are used in the US each year. The racemate is used . Its toxic effect is based on the inhibition of cholinesterase activity . Due to its short half-life of less than a day, it is considered to be easily degradable. In the presence of water or sunlight, it rapidly decomposes into dichlorvos .

Admission

No plant protection products containing this active ingredient are permitted in the EU or Switzerland .

Web links

Naled - Rationale for Naled in TRGS 900 (Federal Institute for Occupational Safety and Health) (PDF; 280 kB).
US EPA: Naled for Mosquito Control .
Frequently Asked Questions about Naled (PDF; 28 kB).

Individual evidence

↑ ^a ^b ^c ^d ^e ^f ^g ^h ⁱ Entry on Naled in the GESTIS substance database of the IFA , accessed on February 8, 2018(JavaScript required) .
↑ entry to naled in ChemIDplus database of the United States National Library of Medicine (NLM), accessed on 11 June 2017th
↑ WHO / FAO Data Sheet on Pesticides (PDS) for Naled ( Memento from July 2, 2014 in the Internet Archive )
↑ Entry on Naled in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on February 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .
↑ Swiss Accident Insurance Fund (Suva): Limit values - current MAK and BAT values (search for 300-76-5 or Naled ), accessed on November 2, 2015.
↑ Caroline Cox: Insecticide Factsheet - Naled (Dibroma) . Journal of Pesticide Reform Fall 2002: 22 (3), 16-21. ( Memento of July 2, 2010 in the Internet Archive ) (PDF; 93 kB).
↑ Data sheet Naled at alanwood.net.
↑ Data sheet Naled in Extoxnet.
^ Directorate-General for Health and Food Safety of the European Commission: Entry on Naled in the EU pesticide database ; Entry in the national registers of plant protection products in Switzerland , Austria and Germany ; accessed on March 26, 2016.

[GESTIS-1] ↑ ^a ^b ^c ^d ^e ^f ^g ^h ⁱ Entry on Naled in the GESTIS substance database of the IFA , accessed on February 8, 2018(JavaScript required) .

[2] try to naled in ChemIDplus database of the United States National Library of Medicine (NLM), accessed on 11 June 2017th

[3] WHO / FAO Data Sheet on Pesticides (PDS) for Naled ( Memento from July 2, 2014 in the Internet Archive )

[CLP_100.005.545-4] Entry on Naled in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on February 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .

[5] Swiss Accident Insurance Fund (Suva): Limit values - current MAK and BAT values (search for 300-76-5 or Naled ), accessed on November 2, 2015.

[6] Caroline Cox: Insecticide Factsheet - Naled (Dibroma) . Journal of Pesticide Reform Fall 2002: 22 (3), 16-21. ( Memento of July 2, 2010 in the Internet Archive ) (PDF; 93 kB).

[7] Data sheet Naled at alanwood.net.

[8] Data sheet Naled in Extoxnet.

[9] Directorate-General for Health and Food Safety of the European Commission: Entry on Naled in the EU pesticide database ; Entry in the national registers of plant protection products in Switzerland , Austria and Germany ; accessed on March 26, 2016.