Palladobismuto arsenide

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Palladobismuto arsenide
General and classification
chemical formula Pd 2 (As, Bi)
Mineral class
(and possibly department)
Sulfides and sulfosalts
System no. to Strunz
and to Dana
2.AC.25 ( 8th edition : II / A.05)
2.4.15.1
Crystallographic Data
Crystal system orthorhombic
Crystal class ; symbol mm 2 or mmm
Space group Pmcn or P2 1 cn
Lattice parameters a  = 7.504  Å ; b  = 18.884 Å; c  = 6.841 Å Please complete the source as an individual reference!
Formula units Z  = 20 Please complete the source as an individual reference!
Physical Properties
Mohs hardness 5
Density (g / cm 3 ) 10.8
Cleavage Please complete!
colour silver-white
Line color Please complete!
transparency opaque
shine metallic

Palladobismuto arsenide is a very rarely occurring mineral from the mineral class of sulfides and sulfosalts . It crystallizes in the orthorhombic crystal system with the chemical composition Pd 2 (As, Bi) and forms irregularly shaped grains up to 165 μm in size with a creamy-white color.

Etymology and history

The mineral was discovered in 1976 by LJ Cabri, TT Chen, JW Stewart and JHG Laflamme in its type locality , the Stillwater Complex in the US state of Montana . It is named after the elements palladium , bismuth and arsenic it contains.

classification

In the Strunz system , palladobismuto arsenide is one of the alloys and alloy-like compounds, a sub-group of sulfides and sulfosalts. After the 8th edition , it forms a group together with arsenopalladinite , athenite , genenkinite , itoigawaite , mayakite , menshikovite , mertieite-I , mertieite-II , palladoarsenide , palladodymite , polkanovite , rhodarsenide , stibiopalladinite , stillwaterite , ungavaite and vincentite . In the 9th edition it forms with mayakite, naldrettite , pallado arsenide, palladodymite and rhod arsenide a subgroup of the compounds of semi-metals with platinum group elements (PGE).

In the systematics according to Dana , which is mainly used in the English-speaking world , it forms its own subgroup of sulfides, selenides and tellurides with the composition A m B n X p , with (m + n): p = 2: 1.

Education and Locations

Palladobismuto arsenide is formed in heavy metal concentrates. It is associated with pallado arsenide and calcite .

Only a few locations are known of the very rare mineral. In addition to its type locality, only one other site is known so far on the Kola Peninsula in Russia .

Crystal structure

Palladobismutoarsenide crystallizes in the orthorhombic crystal system in the space group Pmcn or P2 1 cn with the lattice parameters a = 7.504  Å , b = 18.884 Å and c = 6.841 Å as well as 20 formula units per unit cell .

See also

Individual evidence

  1. ^ New Dana Classification of Sulfide Minerals

literature

Web links