Pigment yellow 83

Structural formula
General
Surname	Pigment yellow 83
other names	2,2 '- {[3,3'-Dichloro (1,1'-biphenyl) -4,4'-diyl] bis (azo) bis- N - (4-chloro-2,5-dimethoxyphenyl) -3 -oxobutyramide}; Pigment yellow 83; CI 21108 ( INCI ) ;
Molecular formula	C 36 H 32 Cl 4 N 6 O 8
Brief description	yellow solid
External identifiers / databases
EC number	226-939-8
ECHA InfoCard	100.024.491
PubChem	21733
ChemSpider	20428
Wikidata	Q16977693
properties
Molar mass	818.50 g mol −1
Physical state	firmly
density	1.50 g cm −3
solubility	practically insoluble in water (<8.1 µg l −1 at 23 ° C)
safety instructions
GHS labeling of hazardous substances	no GHS pictograms
	no GHS pictograms
H and P phrases	H: no H-phrases
	P: no P-phrases
Toxicological data	> 2000 mg kg −1 ( LD 50 , rat , oral )
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

CI Pigment Yellow 83 is a chemical compound from the group of the disazo and diaryl - pigments .

Extraction and presentation

Pigment Yellow 83 is produced industrially by tetrazotization of 3,3'-dichlorobenzidine , followed by azo coupling to the acetoacetylated chloro-4-2,5-dimethoxyaniline recovered.

properties

Pigment Yellow 83 is a flammable, hardly ignitable, yellow solid that is practically insoluble in water. It decomposes when heated above 300 ° C. It has a crystal structure with space group P 2 ₁ / c (space group no. 14) or space group Pc (space group no. 7) . Template: room group / 14 Template: room group / 7

use

Pigment Yellow 83 is used as a reddish yellow pigment, for example for printing inks and plastics.

Individual evidence

↑ Entry on CI 21108 in the CosIng database of the EU Commission, accessed on March 31, 2020.
↑ ^a ^b ^c ^d ^e ^f ^g Entry on Pigment Yellow 83 in the GESTIS substance database of the IFA , accessed on March 30, 2020(JavaScript required) .
↑ ^a ^b Werner Baumann, Thomas Rothardt: Printing chemicals data and facts on environmental protection 2nd, expanded and revised edition . Springer-Verlag, 2013, ISBN 978-3-642-58474-9 , pp. 585 ( limited preview in Google Book search).
↑ External identifiers or database links for 4-chloro-2,5-dimethoxyaniline : CAS number: 6358-64-1, EC number: 228-782-0, ECHA -InfoCard: 100.026.165 , GESTIS- Substance database : 18700 , PubChem : 22833 , ChemSpider : 21398 , Wikidata : Q27289721 .

^ ^A ^b Martin U. Schmidt, Robert E. Dinnebier, Holger Kalkhof: Crystal Engineering on Industrial Diaryl Pigments Using Lattice Energy Minimizations and X-ray Powder Diffraction. In: The Journal of Physical Chemistry B. 111, 2007, p. 9722, doi : 10.1021 / jp071731p .

↑ Willy Herbst, Klaus Hunger: Industrial organic pigments production, properties, application . John Wiley & Sons, 2009, ISBN 3-527-62496-1 , pp. 261 ( limited preview in Google Book search).

[CosIng-1] Entry on CI 21108 in the CosIng database of the EU Commission, accessed on March 31, 2020.

[GESTIS-2] ↑ ^a ^b ^c ^d ^e ^f ^g Entry on Pigment Yellow 83 in the GESTIS substance database of the IFA , accessed on March 30, 2020(JavaScript required) .

[Werner_Baumann,_Thomas_Rothardt-3] Werner Baumann, Thomas Rothardt: Printing chemicals data and facts on environmental protection 2nd, expanded and revised edition . Springer-Verlag, 2013, ISBN 978-3-642-58474-9 , pp. 585 ( limited preview in Google Book search).

[4] External identifiers or database links for 4-chloro-2,5-dimethoxyaniline : CAS number: 6358-64-1, EC number: 228-782-0, ECHA -InfoCard: 100.026.165 , GESTIS- Substance database : 18700 , PubChem : 22833 , ChemSpider : 21398 , Wikidata : Q27289721 .

[DOI10.1021/jp071731p-5] A ^b Martin U. Schmidt, Robert E. Dinnebier, Holger Kalkhof: Crystal Engineering on Industrial Diaryl Pigments Using Lattice Energy Minimizations and X-ray Powder Diffraction. In: The Journal of Physical Chemistry B. 111, 2007, p. 9722, doi : 10.1021 / jp071731p .

[Willy_Herbst,_Klaus_Hunger-6] Willy Herbst, Klaus Hunger: Industrial organic pigments production, properties, application . John Wiley & Sons, 2009, ISBN 3-527-62496-1 , pp. 261 ( limited preview in Google Book search).