Allidochlor

Structural formula
General
Surname	Allidochlor
other names	N , N -diallyl-2-chloroacetamide; Randox; CDAA;
Molecular formula	C 8 H 12 ClNO
Brief description	oily, amber-colored liquid
External identifiers / databases
EC number	202-270-7
ECHA InfoCard	100.002.065
PubChem	7157
Wikidata	Q17310226
properties
Molar mass	173.64 g mol −1
Physical state	liquid
density	1.04 g cm −3
Melting point	25 ° C
boiling point	116 ° C (1 mm Hg)
solubility	practically insoluble in water (20 mg l −1 at 20 ° C)
Refractive index	1.4932
safety instructions
H and P phrases	H: 312-302-319-315-411
	P: 273-280-305 + 351 + 338
Toxicological data	290 mg kg −1 ( LD 50 , rat , oral ) ; 700–760 mg kg −1 ( LD 50 , rat , oral ) ; 830 mg kg −1 ( LD 50 , rat , transdermal ) ;
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

Allidochlor is a chemical compound from the group of chloroacetamides , the herbicidal effect of which was found by Monsanto in 1952 . Allidochlor was the first successful pre-emergence herbicide .

Extraction and presentation

Allidochlor can be obtained by reacting chloroacetic acid chloride with diallylamine .

toxicology

Allidochlor is very irritating to the skin.

Admission

Allidochlor is not approved as a crop protection agent in the European Union or Switzerland .

Individual evidence

↑ ^a ^b ^c ^d ^e Entry on allidochlor in the Pesticide Properties DataBase (PPDB) of the University of Hertfordshire , accessed on June 11, 2014.
↑ ^a ^b David R. Lide (Ed.): CRC Handbook of Chemistry and Physics . 90th edition. (Internet version: 2010), CRC Press / Taylor and Francis, Boca Raton, FL, Physical Constants of Organic Compounds, pp. 3-98.
↑ Robert Krieger (Ed.): Hayes' Handbook of Pesticide Toxicology, Volume 1 . Elsevier, 1999, ISBN 978-0-12-374367-1 , pp. 769 ( limited preview in Google Book search).
↑ Entry on allidochlor in the GESTIS substance database of the IFA , accessed on July 23, 2016(JavaScript required) .
↑ Entry on allidochlor in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on August 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .
↑ Data sheet Allidochlor, PESTANAL at Sigma-Aldrich , accessed on October 20, 2016 ( PDF ).
↑ ^a ^b Toxicology of amide herbicides in horses
↑ Patent US2864683 : Selective method of inhibiting preemergent growth of grasses. Applied on September 13, 1954 , published December 16, 1958 , Applicant: Monsanto Chemicals, Inventor: Philip C Hamm, Angelo J Speziale. ‌
^ Robert L. Zimdahl: A History of Weed Science in the United States . Elsevier Insights, 2010, ISBN 978-0-12-381495-1 , pp. 103 ( limited preview in Google Book search).
↑ Thomas A. Unger: Pesticide Synthesis Handbook . William Andrew, 1996, ISBN 0-8155-1853-6 , pp. 9 ( limited preview in Google Book search).
^ Directorate-General for Health and Food Safety of the European Commission: EU pesticide database ; Entry in the national directory of plant protection products in Switzerland ; Retrieved June 25, 2016.

[ppdb-1] Entry on allidochlor in the Pesticide Properties DataBase (PPDB) of the University of Hertfordshire , accessed on June 11, 2014.

[crc-2] David R. Lide (Ed.): CRC Handbook of Chemistry and Physics . 90th edition. (Internet version: 2010), CRC Press / Taylor and Francis, Boca Raton, FL, Physical Constants of Organic Compounds, pp. 3-98.

[hayes-3] Robert Krieger (Ed.): Hayes' Handbook of Pesticide Toxicology, Volume 1 . Elsevier, 1999, ISBN 978-0-12-374367-1 , pp. 769 ( limited preview in Google Book search).

[GESTIS-4] Entry on allidochlor in the GESTIS substance database of the IFA , accessed on July 23, 2016(JavaScript required) .

[CLP_100.002.065-5] Entry on allidochlor in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on August 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .

[Sigma-6] Data sheet Allidochlor, PESTANAL at Sigma-Aldrich , accessed on October 20, 2016 ( PDF ).

[vetpharm-7] Toxicology of amide herbicides in horses

[8] Patent US2864683 : Selective method of inhibiting preemergent growth of grasses. Applied on September 13, 1954 , published December 16, 1958 , Applicant: Monsanto Chemicals, Inventor: Philip C Hamm, Angelo J Speziale. ‌

[9] Robert L. Zimdahl: A History of Weed Science in the United States . Elsevier Insights, 2010, ISBN 978-0-12-381495-1 , pp. 103 ( limited preview in Google Book search).

[unger-10] Thomas A. Unger: Pesticide Synthesis Handbook . William Andrew, 1996, ISBN 0-8155-1853-6 , pp. 9 ( limited preview in Google Book search).

[11] Directorate-General for Health and Food Safety of the European Commission: EU pesticide database ; Entry in the national directory of plant protection products in Switzerland ; Retrieved June 25, 2016.