Bendiocarb

Structural formula
General
Surname	Bendiocarb
other names	2,2-dimethyl-1,3-benzodioxol-4-yl- N -methylcarbamate; 2,3-isopropylidenedioxy-phenyl- N -methylcarbamate; Seedoxin;
Molecular formula	C 11 H 13 NO 4
Brief description	colorless solid with a slightly aromatic odor
External identifiers / databases
EC number	245-216-8
ECHA InfoCard	100.041.091
PubChem	2314
Wikidata	Q417017
properties
Molar mass	223.23 g mol −1
Physical state	firmly
density	1.25 g cm −3
Melting point	124.6 ° C (decomposition)
solubility	very sparingly soluble in water (260 mg l −1 at 25 ° C); soluble in benzene , ethanol , chloroform , dichloromethane , dioxane and dimethylformamide ;
safety instructions
H and P phrases	H: 300-311-331-410
	P: 261-273-280-301 + 310-311-501
Toxicological data	40 mg kg −1 ( LD 50 , rat , oral )
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Bendiocarb is a chemical compound from the group of substituted oxygen-containing heterocycles and carbamates that is used as an insecticide .

history

Bendiocarb was first produced in 1971 and brought onto the market by the British company Fisons. It is currently marketed by Bayer CropScience and Kuo Ching under various trade names: Ficam, Dycarb, Garvox, Turcam, Niomil, Seedox, Tatoos.

properties

Bendiocarb is a flammable, colorless solid with a slightly aromatic odor, which is very sparingly soluble in water. It decomposes above its melting temperature. In aqueous suspensions, hydrolysis is slow and in alkaline solutions rapid hydrolysis to phenol (NC 7312).

use

Biocide

According to Directive 98/8 / EC of February 16, 1998, biocidal products should only be permitted whose active ingredients have been included in the appendix (Appendix I, IA and IB) of the aforementioned directive (for the defined product type). According to the transitional regulation (Art. 16 (1) of Directive 98/8 / EC), the placing on the market of biocidal products that do not contain the active substances listed in the annex to Directive 98/8 / EC, provided that these active substances with the reference date May 14th 2000 were already on the market (also called "old active ingredients").

According to Regulation (EC) 1896/2000 of September 7, 2000, manufacturers who wanted to apply for the inclusion of an “old active substance” in Annexes I, IA and IB had to notify the relevant active substance for the corresponding product type by March 28, 2002 have reported. This period was extended to January 31, 2003 by Regulation (EC) 1687/2000 of September 25, 2002. The “notified active substances” were allowed to remain on the market until the final decision on inclusion or non-inclusion in Annex I, IA and IB of EU Directive 98/8 / EC.

With Regulation (EC) 2032/2003 of November 4, 2003, the active ingredient bendiocarb was added to the list (Appendix II) of notified active ingredients for product type 18 (insecticides).

With Regulation (EC) 1451/2007 of December 4, 2007 on the second phase of the ten-year work program on placing biocidal products on the market, the active ingredient bendiocarb was included in the final list (Annex II) of those to be examined within the framework of the test program Active ingredients added.

With the adoption of Directive 2012/3 / EU of February 9, 2012, a decision has been made to include the active ingredient bendiocarb in the corresponding list (Annex I of Directive 98/8 / EC) for product type 18 (insecticides) from February 1, 2014 . The sale of biocidal products containing the active ingredient bendiocarb is therefore still permitted in the EU (Switzerland has adopted this provision) for product type 18 (insecticides) (initially limited to January 31, 2024).

Pesticides

The active ingredient was mainly used against the Colorado potato beetle and for seed dressing in sugar beet and fodder beetle against the poppy beetle . It was also used against garden and lawn ants . Bendiocarb was marketed as a wettable powder, seed powder, aerosol or granulate. Beet pill seed was also available which, in addition to bendiocarb, contained the fungicide thiram .

Bendiocarb is not on the list of active ingredients in plant protection products permitted in the EU . In the EU states such as Germany and Austria as well as in Switzerland no pesticides with this active ingredient are approved.

Individual evidence

↑ ^a ^b ^c ^d ^e ^f ^g Entry on Bendiocarb in the GESTIS substance database of the IFA , accessed on January 8, 2018(JavaScript required) .
↑ Joint Meeting on Pesticide Residues (JMPR), Monograph for Bendiocarb , accessed December 9, 2014.
↑ Entry on Bendiocarb in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on February 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .
↑ Data bendiocarb at Sigma-Aldrich , accessed on 16 February 2020 ( PDF ).
^ Bendiocarb ( Memento of September 21, 2010 in the Internet Archive ), Pesticides News No. 68, June 2005, pp. 20-21.
↑ EU: Directive 98/8 / EG of February 16, 1998 on the placing of biocidal products on the market . In: Official Journal of the European Communities . L 123, April 24, 1998, pp. 1-63.
↑ EU: Regulation (EC) No. 1896/2000 of September 7, 2000 on the first phase of the program in accordance with Article 16, paragraph 2 of Directive 98/8 / EC on biocidal products . In: Official Journal of the European Communities. L 228, September 8, 2000, pp. 6-17.
↑ EU: Regulation (EC) No. 1687/2002 of September 25, 2002 on an additional deadline for the notification of certain active substances . In: Official Journal of the European Communities. L 258, September 26, 2002, pp. 15-16.
↑ EU: Regulation (EC) No. 2032/2003 of November 4, 2003 on the second phase of the ten-year work program on placing biocidal products on the market . In: Official Journal of the European Communities. L 307, November 24, 2003, p. 1.
↑ EU: Regulation (EC) No. 1451/2007 of December 4, 2007 on the second phase of the ten-year work program on placing biocidal products on the market . In: Official Journal of the European Communities. L 325, December 11, 2007, pp. 3-65.
↑ EU Directive 2012/3 / EU of 9 February 2012 amending Directive 98/8 / EC to include the active ingredient bendiocarb in Annex I . In: Official Journal of the European Communities. L 37, February 10, 2012, pp. 65-67.
↑ Werner Perkow: Active substances in pesticides and pesticides . 4th supplementary edition, May 1994, Paul Parey publishing house.
↑ Regulation (EC) No. 2076/2002 of the Commission of November 20, 2002 extending the deadline in accordance with Article 8 (2) of Council Directive 91/414 / EEC and on the non-inclusion of certain active substances in Annex I of this directive and the revocation of the Approvals of plant protection products with these active ingredients .
↑ General Directorate Health and Food Safety of the European Commission: Entry on Bendiocarb in the EU pesticide database; Entry in the national registers of plant protection products in Switzerland , Austria and Germany ; Retrieved March 3, 2016.

[GESTIS-1] ↑ ^a ^b ^c ^d ^e ^f ^g Entry on Bendiocarb in the GESTIS substance database of the IFA , accessed on January 8, 2018(JavaScript required) .

[2] Joint Meeting on Pesticide Residues (JMPR), Monograph for Bendiocarb , accessed December 9, 2014.

[CLP_100.041.091-3] Entry on Bendiocarb in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on February 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .

[SigmaAldrich-4] Data bendiocarb at Sigma-Aldrich , accessed on 16 February 2020 ( PDF ).

[5] Bendiocarb ( Memento of September 21, 2010 in the Internet Archive ), Pesticides News No. 68, June 2005, pp. 20-21.

[6] EU: Directive 98/8 / EG of February 16, 1998 on the placing of biocidal products on the market . In: Official Journal of the European Communities . L 123, April 24, 1998, pp. 1-63.

[7] EU: Regulation (EC) No. 1896/2000 of September 7, 2000 on the first phase of the program in accordance with Article 16, paragraph 2 of Directive 98/8 / EC on biocidal products . In: Official Journal of the European Communities. L 228, September 8, 2000, pp. 6-17.

[8] EU: Regulation (EC) No. 1687/2002 of September 25, 2002 on an additional deadline for the notification of certain active substances . In: Official Journal of the European Communities. L 258, September 26, 2002, pp. 15-16.

[9] EU: Regulation (EC) No. 2032/2003 of November 4, 2003 on the second phase of the ten-year work program on placing biocidal products on the market . In: Official Journal of the European Communities. L 307, November 24, 2003, p. 1.

[10] EU: Regulation (EC) No. 1451/2007 of December 4, 2007 on the second phase of the ten-year work program on placing biocidal products on the market . In: Official Journal of the European Communities. L 325, December 11, 2007, pp. 3-65.

[11] EU Directive 2012/3 / EU of 9 February 2012 amending Directive 98/8 / EC to include the active ingredient bendiocarb in Annex I . In: Official Journal of the European Communities. L 37, February 10, 2012, pp. 65-67.

[Perkow-12] Werner Perkow: Active substances in pesticides and pesticides . 4th supplementary edition, May 1994, Paul Parey publishing house.

[13] Regulation (EC) No. 2076/2002 of the Commission of November 20, 2002 extending the deadline in accordance with Article 8 (2) of Council Directive 91/414 / EEC and on the non-inclusion of certain active substances in Annex I of this directive and the revocation of the Approvals of plant protection products with these active ingredients .

[PSM-14] General Directorate Health and Food Safety of the European Commission: Entry on Bendiocarb in the EU pesticide database; Entry in the national registers of plant protection products in Switzerland , Austria and Germany ; Retrieved March 3, 2016.