Binapacryl

Structural formula
General
Surname	Binapacryl
other names	(6- (1-methylpropyl) -2,4-dinitrophenyl) -3,3-dimethyl acrylate; 2-sec-butyl-4,6-dinitrophenyl-3-methyl-2-butenoate; 2-sec-butyl-4,6-dinitrophenyl-beta, beta-dimethylacrylic acid ester; Acricid; (2- (1-methylpropyl) -4,6-dinitrophenyl) -3,3-dimethyl acrylate; 2-sec-butyl-4,6-dinitrophenyl-3-methyl crotonate;
Molecular formula	C 15 H 18 N 2 O 6
Brief description	yellow to brown solid with a characteristic odor
External identifiers / databases
EC number	207-612-9
ECHA InfoCard	100.006.921
PubChem	10234
Wikidata	Q3468507
properties
Molar mass	322.32 g mol −1
Physical state	firmly
density	1.24 g cm −3 (bulk density)
Melting point	66-67 ° C
Vapor pressure	13 mPa (25 ° C)
solubility	practically insoluble in water (1 mg l −1 at 20 ° C); soluble in acetone, xylene and ethanol;
safety instructions
H and P phrases	H: 360D-312-302-410
	P: 201-273-280-308 + 313-501
Toxicological data	58 mg kg −1 ( LD 50 , rat , oral ) ; 750 mg kg −1 ( LD 50 , rabbit , transdermal ) ;
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Binapacryl is a chemical compound from the group of dinitrophenols .

Extraction and presentation

Binapacryl can be obtained by esterifying dinoseb with 3-methylcrotonoyl chloride.

properties

Binapacryl is a flammable, yellow to brown solid with a characteristic odor, which is practically insoluble in water. It decomposes when heated. The compound is stable under normal environmental conditions, but slowly degrades when exposed to UV light.

use

Binapacryl is used as a fungicide , insecticide and acaricide .

Admission

In the European Union, binapacryl is not only not permitted, it is prohibited. In Germany, Austria and Switzerland, no pesticides with this active ingredient are permitted.

Individual evidence

↑ ^a ^b ^c ^d ^e ^f ^g ^h Entry on Binapacryl in the GESTIS substance database of the IFA , accessed on February 1, 2016(JavaScript required) .
↑ ^a ^b ^c ^d Entry on Binapacryl in the Pesticide Properties DataBase (PPDB) of the University of Hertfordshire , accessed on August 1, 2013.
↑ Entry on Binapacryl in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on August 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .
↑ Binapacryl data sheet , PESTANAL at Sigma-Aldrich , accessed on May 19, 2017 ( PDF ).
^ Entry on Binapacryl in the Hazardous Substances Data Bank , accessed on March 13, 2013.
↑ Thomas A. Unger: Pesticide Synthesis Handbook . William Andrew, 1996, ISBN 0-08-095716-1 , pp. 881 ( limited preview in Google Book Search).
^ Joint Meeting on Pesticide Residues (JMPR), Monograph for Binapacryl , accessed December 9, 2014.
↑ General Directorate Health and Food Safety of the European Commission: Entry on Binapacryl in the EU pesticide database; Entry in the national registers of plant protection products in Switzerland , Austria and Germany ; accessed on February 24, 2016.

[GESTIS-1] ↑ ^a ^b ^c ^d ^e ^f ^g ^h Entry on Binapacryl in the GESTIS substance database of the IFA , accessed on February 1, 2016(JavaScript required) .

[herts.ac.uk-2] Entry on Binapacryl in the Pesticide Properties DataBase (PPDB) of the University of Hertfordshire , accessed on August 1, 2013.

[CLP_100.006.921-3] Entry on Binapacryl in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on August 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .

[Sigma-4] Binapacryl data sheet , PESTANAL at Sigma-Aldrich , accessed on May 19, 2017 ( PDF ).

[HSDB-5] Entry on Binapacryl in the Hazardous Substances Data Bank , accessed on March 13, 2013.

[Thomas_A._Unger-6] Thomas A. Unger: Pesticide Synthesis Handbook . William Andrew, 1996, ISBN 0-08-095716-1 , pp. 881 ( limited preview in Google Book Search).

[inchem.org-7] Joint Meeting on Pesticide Residues (JMPR), Monograph for Binapacryl , accessed December 9, 2014.

[PSM-8] General Directorate Health and Food Safety of the European Commission: Entry on Binapacryl in the EU pesticide database; Entry in the national registers of plant protection products in Switzerland , Austria and Germany ; accessed on February 24, 2016.