Lead trinitroresorcinate

Structural formula
General
Surname	Lead trinitroresorcinate
other names	Lead 2,4,6-trinitroresorcinate; Lead-2,4,6-trinitro-m-phenylene dioxide; Lead typhnate; Lead ricinate; Trizinate;
Molecular formula	C 6 HN 3 O 8 Pb
Brief description	orange or reddish brown rhombic explosive crystals
External identifiers / databases
EC number	239-290-0
ECHA InfoCard	100.035.703
PubChem	61789
ChemSpider	21106132
Wikidata	Q425053
properties
Molar mass	450.28 g mol −1
Physical state	firmly
density	3.07 g cm −3 (α modification); 3.01 g cm −3 (β modification);
Melting point	190 ° C (decomposition)
solubility	very heavy in water (0.6-0.9 g / l at 20 ° C)
safety instructions
H and P phrases	H: 200-302-332-360Df-373-410
	P: ?
Authorization procedure under REACH	of particular concern : toxic for reproduction ( CMR )
MAK	not specified because it is carcinogenic
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Lead trinitroresorcinate (also lead styphnate, lead tricinate, trizinate) is the lead salt of styphnic acid , an explosive nitroaromatic . It is used as an initial explosive in detonators and primers .

properties

Lead trinitroresorcinate forms orange-yellow to dark-brown crystals. The non- hygroscopic compound, which is insoluble in diethyl ether , chloroform , benzene and toluene , is poorly soluble in acetone and water (400 ppm ). The impact sensitivity is 2.5-5.0 Nm, the friction sensitivity 1.5 N. The deflagration point is 275 ° C. The detonation speed is 5200 m / s. It is very sensitive to electrostatic charges.

use

Lead trinitroresorcinate is a widespread and widely used initial explosive which , because of its extreme sensitivity to electrostatic charges, is only used in admixture with additives. He is (next tetracene ) the main component of Sinoxid -Anzündhütchen.

Individual evidence

↑ ^a ^b ^c ^d Entry on lead trinitroresorcinate. In: Römpp Online . Georg Thieme Verlag, accessed on March 24, 2014.
↑ ^a ^b ^c Entry on lead-2,4,6-trinitroresorcinate in the GESTIS substance database of the IFA , accessed on February 1, 2016(JavaScript required) .
↑ Entry on lead 2,4,6-trinitro-m-phenylene dioxide in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on February 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .
↑ Entry in the SVHC list of the European Chemicals Agency , accessed on July 17, 2014.
↑ Köhler, J .; Meyer, R .; Homburg, A .: Explosivstoffe , tenth, completely revised edition. Wiley-VCH, Weinheim 2008, ISBN 978-3-527-32009-7 .
↑ The RWS primer cap

[roempp-1] Entry on lead trinitroresorcinate. In: Römpp Online . Georg Thieme Verlag, accessed on March 24, 2014.

[GESTIS-2] Entry on lead-2,4,6-trinitroresorcinate in the GESTIS substance database of the IFA , accessed on February 1, 2016(JavaScript required) .

[CLP_100.035.703-3] Entry on lead 2,4,6-trinitro-m-phenylene dioxide in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on February 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .

[SVHC-4] Entry in the SVHC list of the European Chemicals Agency , accessed on July 17, 2014.

[Explosivstoffe-5] Köhler, J .; Meyer, R .; Homburg, A .: Explosivstoffe , tenth, completely revised edition. Wiley-VCH, Weinheim 2008, ISBN 978-3-527-32009-7 .

[6] The RWS primer cap