Cyclohexylmethanol

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Structural formula
Structural formal of cyclohexylmethanol
General
Surname Cyclohexylmethanol
Molecular formula C 7 H 14 O
Brief description

yellowish liquid with a smell of alcohol

External identifiers / databases
CAS number 100-49-2
EC number 202-857-8
ECHA InfoCard 100,002,598
PubChem 7507
Wikidata Q18213346
properties
Molar mass 114.19 g mol −1
Physical state

liquid

density

0.9339 g cm −3

Melting point

19 ° C

boiling point

187-188 ° C

solubility

low in water

Refractive index

1.4640

safety instructions
GHS labeling of hazardous substances
no GHS pictograms
H and P phrases H: no H-phrases
P: no P-phrases
Toxicological data

910 μmol L −1 ( EC 50 , Rana Pipiens ,  transdermal )

As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

Cyclohexylmethanol is a chemical compound from the class of cycloalkanes and alcohols .

properties

Cyclohexylmethanol has a flash point of 71 ° C.

Manufacturing

Cyclohexylmethanol can be produced from cyclohexene by hydroformylation . Cyclohexane is also formed as a by-product through hydrogenation .

Individual evidence

  1. ↑ a b c Entry on cyclohexylmethanol in the GESTIS substance database of the IFA , accessed on October 4, 2014 (JavaScript required)
  2. ↑ a b Vinzenz Prey, Jürgen Bartsch: Dipole measurements on pyranose and furanose model substances. In: Justus Liebig's Annals of Chemistry. 712, 1968, pp. 201-207, doi: 10.1002 / jlac.19687120124 .
  3. ↑ Bruce Rickborn, Stanley E. Wood: Cleavage of cyclopropanes by diborane. In: Journal of the American Chemical Society. 93, 1971, pp. 3940-3946, doi: 10.1021 / ja00745a021 .
  4. ^ Paul Ruelle, Ulrich W. Kesselring: The hydrophobic propensity of water toward amphiprotic solutes: Predicton and molecular origin of the aqueous solubility of aliphatic alcohols. In: Journal of Pharmaceutical Sciences. 86, 1997, pp. 179-186, doi: 10.1021 / js9603109 .
  5. ↑ a b Data sheet for cyclohexanemethanol from Sigma-Aldrich , accessed on May 25, 2017 ( PDF ).
  6. ^ DE Raines, SE Korten, AG Hill, KW Miller: Anesthetic cutoff in cycloalkanemethanols. A test of current theories. In: Anesthesiology. Volume 78, Number 5, May 1993, pp. 918-927, PMID 8489064 .
  7. ↑ Patent EP2000453 : METHOD FOR PRODUCING ALCOHOL BY USING CARBON DIOXIDE AS RAW MATERIAL. Published on December 10, 2008 , inventor: TOMINAGA KENICHI. ‌