Diethyl aluminum chloride

from Wikipedia, the free encyclopedia
Structural formula
Structure of diethyl aluminum chloride
General
Surname Diethyl aluminum chloride
other names
  • DEAC
  • Diethyl aluminum monochloride
  • Chlorodiethylaluminum
Molecular formula C 4 H 10 AlCl
Brief description

colorless and odorless liquid

External identifiers / databases
CAS number 96-10-6
EC number 202-477-2
ECHA InfoCard 100.002.253
PubChem 7277
Wikidata Q413029
properties
Molar mass 120.56 g · mol -1
Physical state

liquid

density

0.97 g cm −3

Melting point

−74 ° C

boiling point

208 ° C

Vapor pressure

31 Pa (20 ° C)

solubility

violent decomposition in water

safety instructions
GHS labeling of hazardous substances
02 - Highly / extremely flammable 05 - Corrosive

danger

H and P phrases H: 250-260-314
EUH: 014
P: 231 + 232-280-302 + 334-310-370 + 378-402 + 404-501
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Diethyl aluminum chloride is an organometallic compound of aluminum . It is used as a catalyst in the manufacture of chemical products.

use

Diethylaluminum chloride is used as a catalyst in Ziegler-Natta polymerization processes of vinylene , alkenes and dienes as well as linear oligomerizations and cyclizations of unsaturated hydrocarbons . It is also used as a catalyst in alkylation (see also Friedel-Crafts alkylation ). It is also used as an intermediate in the production of other chemicals.

safety instructions

Diethylaluminum chloride ignites spontaneously in air.

Individual evidence

  1. a b c d e f g h Entry on diethylaluminum chloride in the GESTIS substance database of the IFA , accessed on July 23, 2016(JavaScript required) .
  2. Hazardous Substance Fact Sheet: Diethylaluminium chloride , June 2001.