Minimum ignition charge

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The minimum ignition charge (MZQ) describes the ignition sensitivity of a medium, in the actual sense of a flammable substance such as a gas, a liquid or a solid, to discharges of static electricity. It is mainly used for assessing discharges from plastics .

In the "Technical Rules for Hazardous Substances - Avoidance of Ignition Hazards Due to Electrostatic Charges" (TRGS 727, Appendix G), the following minimum ignition charges and minimum ignition energies are listed.

Minimum ignition charges
connection Minimum ignition energy
(mJ)
Minimum ignition
charge (nC)
Most readily ignitable
mixture

(vol .-%)
Explosion
group according to IEC 60079-0
acetaldehyde 0.38 - - IIA
acetone 0.55 127 6.5 IIA
Acrylonitrile 0.16 - 9.0 IIB
ammonia 14th 1500 20th IIA
benzene 0.20 45 4.7 IIA
1,3-butadiene 0.13 - 5.2 IIB
butane 0.25 60 4.7 IIA
2-butanone 0.27 - 5.3 IIA
Cyclohexane 0.22 - 3.8 IIA
Cyclopropane 0.17 - 6.3 IIB
1,2-dichloroethane 1.0 - 10.5 IIA
Dichloromethane 9,300 880,000 18th IIA
Diethyl ether 0.19 40 5.1 IIB
2,2-dimethylbutane 0.25 70 3.4 IIA
Ethyl acetate 0.46 120 5.2 IIA
Ethane 0.25 70 6.5 IIA
Ethanol 0.28 60 6.4 IIB
Ethene 0.082 32 8.0 IIB
Ethine 0.019 - 7.7 IIC
Ethylene oxide 0.061 - 10.8 IIB
Heptane 0.24 60 3.4 IIA
Hexane 0.24 60 3.8 IIA
methane 0.28 70 8.5 IIA
Methanol 0.20 50 14.7 IIA
2-methylbutane 0.21 63 3.8 IIA
Methylcyclohexane 0.27 70 3.5 IIA
Pentane 0.28 63 3.3 IIA
cis-2-pentene 0.18 - 4.4 IIB
trans-2-pentene 0.18 - 4.40 IIB
propane 0.25 70.00 5.20 IIA
1-propyne 0.11 - 6.50 IIB
Propylene oxide 0.13 - 7.50 IIB
Carbon disulfide 0.01 - 7.80 IIC
Tetrafluoroethene 4.10 - - IIA
Tetrahydro-2H-pyran 0.22 60.00 4.70 IIA
1,1,1-trichloroethane 4,800 700,000 12.00 IIA
Trichlorethylene 510.00 150,000 26.00 IIA
hydrogen 0.02 12.00 22.00 IIC

Individual evidence

  1. Ignition hazards due to electrostatic charges: Fundamentals of electrostatics; Information on the implementation of TRBS 2153 with wording . ecomed-Storck, 2009, ISBN 978-3-609-61870-8 , p. 40 ( books.google.de ).
  2. BAuA - TRGS 727 Avoidance of ignition hazards due to electrostatic charges / Technical rules for hazardous substances (TRGS) / Hazardous substances / Topics from AZ / Federal Institute for Occupational Safety and Health. Retrieved March 23, 2017 . , Version July 29, 2016