Rinneit

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Rinneit
Rinneite - Mineralogical Museum Bonn.jpg
Rinnetite (to protect against decomposition due to humidity in the glass) from the Nordhausen potash works, shaft I, Wolkramshausen
General and classification
chemical formula K 3 NaFe 2+ Cl 6
Mineral class
(and possibly department)
Halides
System no. to Strunz
and to Dana
3.CJ.05 ( 8th edition : III / C.06)
05/11/03/01
Crystallographic Data
Crystal system trigonal
Crystal class ; symbol ditrigonal-scalenohedral; 3 m
Space group R 3 c
Lattice parameters a  = 11.98  Å ; c  = 13.84 Å Please complete the source as an individual reference!
Formula units Z  = 6 Please complete the source as an individual reference!
Twinning along {0001}
Physical Properties
Mohs hardness 3
Density (g / cm 3 ) 2,347
Cleavage Please complete!
Break ; Tenacity splintery, mussel-like
colour pure colorless, colorless, pink, violet, brown, yellow
Line color White
transparency translucent
shine silky
Crystal optics
Refractive indices n ω  = 1.589
n ε  = 1.589

Rinneit is a very rare mineral from the mineral class of halides . It crystallizes in the trigonal crystal system with the chemical formula K 3 NaFe 2+ Cl 6 and rarely forms idiomorphic crystals, mostly massive grains that are transparent and colorless in their pure state, otherwise pink, violet, brown or yellow. It is isostructural to chloromanganocalite .

Special properties

The mineral is soluble in water. In ethanol it decomposes to form ferric chloride .

Etymology and history

Rinneit was first found in 1909 by HE Boeke in the type locality Wolkramshausen in Thuringia ( Germany ). It was named after the German mineralogist and crystallographer Friedrich Rinne .

classification

Rinneit belongs to the mineral class of halides. In the 8th edition of the Strunz system , it forms a subgroup of the hydrous double halides with chlorine manganocalite . In the 9th edition, it is one of the complex halides and, together with chloromanganocalite, forms a subgroup of the halides with MX 6 complexes, where M can be iron , manganese or copper .

In the Dana system , it forms a separate subgroup of the complex halides - aluminum fluorides with the formula (A) m B (X) 6 .

Education and Locations

Rinneit is found in salt deposits that have formed when parts of the sea dried up. It is a secondary mineral in evaporite deposits . Rinneit can also form as a sublimate in volcanoes . The mineral is associated with halite , sylvine , kieserite , carnallite , langbeinite and anhydrite .

Finds of the mineral are mainly known from Germany. There it was found in various salt deposits in Hänigsen , Wathlingen , Diekholzen , Groß Giesen and Schwarmstedt in Lower Saxony , Stassfurt in Saxony-Anhalt and Wolkramshausen and Bad Salzungen in Thuringia . Other sites are the Iranian province of Hormozgan , Mount Vesuvius in Italy , Eskdale in England and Austin County in Texas , United States .

Crystal structure

Rinneit crystallizes in the trigonal crystal system in the space group R 3 c with the lattice parameters a = 11.98  Å and c = 13.84 Å, as well as six formula units per unit cell .

See also

Individual evidence

  1. ^ New Dana Classification of complex halides

literature

  • Rinneit in: Anthony et al .: Handbook of Mineralogy , 1990, 1, 101 ( pdf )

Web links

Commons : Rinnetite  - collection of images, videos and audio files