Benzyl acetate

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Structural formula
Structural formula of benzyl acetate
General
Surname Benzyl acetate
other names
  • Benzyl acetate
  • Ethanoic acid benzyl ester
Molecular formula C 9 H 10 O 2
Brief description

colorless liquid with a characteristic odor

External identifiers / databases
CAS number 140-11-4
EC number 205-399-7
ECHA InfoCard 100,004,909
PubChem 8455
Wikidata Q424223
properties
Molar mass 150.18 g mol −1
Physical state

liquid

density

1.06 g cm −3

Melting point

−51 ° C

boiling point

214 ° C

Vapor pressure

0.19 mbar (25 ° C)

solubility
  • very heavy in water (<1 g l −1 at 23 ° C)
  • soluble in ethanol and ether
Refractive index

1.5232 (20 ° C)

safety instructions
GHS labeling of hazardous substances
no GHS pictograms
H and P phrases H: 412
P: 273
Toxicological data

2490 mg kg −1 ( LD 50ratoral )

As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

Benzyl acetate is a chemical compound from the group of carboxylic acid esters .

Occurrence

Benzyl acetate occurs naturally in many fruits, mushrooms and especially flowers and their oils (for example jasmine oil and ylang-ylang oil ).

Extraction and presentation

Benzyl acetate can be obtained by reacting benzyl alcohol with acetic acid and sodium acetate or benzyl chloride with alkali acetates .

use

Because of its flowery smell, benzyl acetate is mainly used as a fragrance and also as a solvent (e.g. for cellulose acetates and nitrates, oils, lacquers, polishes and inks) and is contained in printing inks, lacquers and leveling agents in coating materials.

safety instructions

The vapors of benzyl acetate can form an explosive mixture with air ( flash point 102 ° C, ignition temperature 460 ° C).

Web links

Individual evidence

  1. a b c d e f g h i Entry on benzyl acetate in the GESTIS substance database of the IFA , accessed on January 10, 2017(JavaScript required) .
  2. Data sheet acetic acid benzyl ester (PDF) from Merck , accessed on February 23, 2010.
  3. David R. Lide (Ed.): CRC Handbook of Chemistry and Physics . 90th edition. (Internet version: 2010), CRC Press / Taylor and Francis, Boca Raton, FL, Physical Constants of Organic Compounds, pp. 3-42.
  4. International Agency for Research on Cancer (IARC): Benzyl Acetate .
  5. Entry on benzyl acetate. In: Römpp Online . Georg Thieme Verlag, accessed on June 15, 2014.

Related links