2-ethylaniline

Structural formula
General
Surname	2-ethylaniline
other names	o -ethylaniline; 1-amino-2-ethylbenzene; 2-aminoethylbenzene;
Molecular formula	C 8 H 11 N
Brief description	yellow-orange liquid with an aromatic odor
External identifiers / databases
EC number	209-424-2
ECHA InfoCard	100.008.569
PubChem	11357
ChemSpider	13860641
Wikidata	Q16322539
properties
Molar mass	121.18 g mol −1
Physical state	liquid
density	0.98 g cm −3
Melting point	−46 ° C
boiling point	210 ° C
Vapor pressure	<0.1 hPa (50 ° C)
solubility	practically insoluble in water; soluble in ethanol and toluene;
Refractive index	1.559 (20 ° C)
safety instructions
H and P phrases	H: 302-311-319
	P: 261-280-311
Toxicological data	1260 mg kg −1 ( LD 50 , rat , oral )
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

2-Ethylaniline is a chemical compound from the group of aniline derivatives .

Extraction and presentation

2-Ethylaniline can be obtained by ethylating aniline using ethene and aluminum trichloride / aluminum as catalysts at a pressure of approx. 200 bar in an autoclave .

properties

2-Ethylaniline is a flammable, hardly flammable, yellow-orange liquid with an aromatic odor, which is practically insoluble in water. It turns brown in air.

use

2-Ethylaniline is used as an intermediate in the manufacture of drugs (e.g. Etodolac ), pesticides, and other chemical compounds.

safety instructions

The vapors of 2-ethylaniline can form an explosive mixture with air ( flash point 92 ° C, ignition temperature approx. 515 ° C).

Individual evidence

↑ ^a ^b ^c ^d ^e ^f ^g ^h ⁱ ^j ^k Entry on 2-ethylaniline in the GESTIS substance database of the IFA , accessed on January 9, 2019(JavaScript required) .
^ ^A ^b Robert A. Lewis: Hawley's Condensed Chemical Dictionary . John Wiley & Sons, 2016, ISBN 978-1-119-26784-3 , pp. 575 ( limited preview in Google Book search).
↑ ^a ^b Data sheet 2-Ethylaniline, 98% from Sigma-Aldrich , accessed on December 2, 2016 ( PDF ).
^ Wilhelm Foerst: Newer Methods of Preparative Organic Chemistry . Elsevier, 1963, ISBN 978-0-323-15042-2 , pp. 230 ( limited preview in Google Book search).
↑ Richard P. Pohanish: Sittig's Handbook of Toxic and Hazardous Chemicals and Carcinogens . William Andrew, 2011, ISBN 978-1-4377-7870-0 , pp. 1198 ( limited preview in Google Book search).

[GESTIS-1] ↑ ^a ^b ^c ^d ^e ^f ^g ^h ⁱ ^j ^k Entry on 2-ethylaniline in the GESTIS substance database of the IFA , accessed on January 9, 2019(JavaScript required) .

[Robert_A._Lewis-2] A ^b Robert A. Lewis: Hawley's Condensed Chemical Dictionary . John Wiley & Sons, 2016, ISBN 978-1-119-26784-3 , pp. 575 ( limited preview in Google Book search).

[Sigma-3] Data sheet 2-Ethylaniline, 98% from Sigma-Aldrich , accessed on December 2, 2016 ( PDF ).

[Wilhelm_Foerst-4] Wilhelm Foerst: Newer Methods of Preparative Organic Chemistry . Elsevier, 1963, ISBN 978-0-323-15042-2 , pp. 230 ( limited preview in Google Book search).

[Richard_P._Pohanish-5] Richard P. Pohanish: Sittig's Handbook of Toxic and Hazardous Chemicals and Carcinogens . William Andrew, 2011, ISBN 978-1-4377-7870-0 , pp. 1198 ( limited preview in Google Book search).