Triallate

Structural formula
General
Surname	Triallate
other names	S -2,3,3-trichloroallyl- N , N -diisopropylthiocarbamate N , N -diisopropyl-2,3,3-trichloroallylthiol carbamate
Molecular formula	C 10 H 16 Cl 3 NOS
Brief description	colorless, flammable powder
External identifiers / databases
CAS number 2303-17-5 EC number 218-962-7 ECHA InfoCard 100.017.239 PubChem 5543 Wikidata Q904371
properties
Molar mass	304.67 g · mol -1
Physical state	firmly
density	1.27 g cm −3 (25 ° C)
Melting point	29-30 ° C
boiling point	117 ° C (0.0004 hPa)
Vapor pressure	0.00012 mmHg (25 ° C)
solubility	practically insoluble in water (4.0 mg l −1 at 20 ° C)
safety instructions
GHS hazard labeling from  Regulation (EC) No. 1272/2008 (CLP) , expanded if necessary Caution H and P phrases H: 302-317-373-410 P: 273-280-501
Toxicological data	800 mg kg −1 ( LD 50 ,  rat ,  oral )
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions .

Triallat is an active ingredient for crop protection and a chemical compound from the group of thiocarbamates .

history

Triallat was introduced to the market by the Monsanto company in the 1960s .

use

Triallate is as herbicide (interfere with the cell division processes) for the control of wild oats and Windhalm in cereals (except oats ) in beet , corn , vegetables and forage peas used. It is used for this in liquid form (dissolved e.g. in acetonitrile ).

Admission

In some EU countries, Triallat is approved as a plant protection product , but not in Germany, Austria and Switzerland.

safety instructions

At higher temperatures, triallate is unstable and decomposes, producing nitrogen oxides , hydrogen chloride and sulfur oxides .

See also

• Dialate

Individual evidence

1. ↑ ^{a b c d e f g} Entry on Triallat in the GESTIS substance database of the IFA , accessed on February 1, 2016(JavaScript required) .
2. ↑ Entry on Triallate in the ChemIDplus database of the United States National Library of Medicine (NLM), accessed on June 16, 2017.
3. ↑ Weber, JB: Interaction of organic pesticides with particulate matter in aquatic and soil systems in Fate of Organic Pesticides in the Aquatic Environment, Adv. Chem. Ser. 111 (1972) 55.
4. ↑ Entry on Tri-allate in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on February 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .
5. ↑ Entry on Triallate in the ChemIDplus database of the United States National Library of Medicine (NLM) .
6. ↑ More knowledge for best performance ( Memento from October 21, 2007 in the Internet Archive ) Manufacturers' Compendium Roundup from September 12, 2006.
7. ↑ Description of the application .
8. ↑ General Directorate Health and Food Safety of the European Commission: Entry on Tri-allate in the EU pesticide database ; Entry in the national registers of plant protection products in Switzerland , Austria and Germany ; accessed on March 12, 2016.