1-chlorohexane

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Structural formula
Structural formula of 1-chlorohexane
General
Surname 1-chlorohexane
other names

Hexyl chloride

Molecular formula C 6 H 13 Cl
Brief description

colorless liquid with an aromatic odor

External identifiers / databases
CAS number 544-10-5
EC number 208-859-5
ECHA InfoCard 100.008.054
PubChem 10992
Wikidata Q15726107
properties
Molar mass 120.62 g mol −1
Physical state

liquid

density

0.88 g cm −3

Melting point

−94 ° C

boiling point

135 ° C

Vapor pressure

6.65 hPa (15 ° C)

solubility
Refractive index

1.419 (20 ° C)

safety instructions
GHS labeling of hazardous substances
02 - Highly / extremely flammable

Caution

H and P phrases H: 226
P: 210-280-370 + 378-403 + 235
Toxicological data

7000 mg kg −1 ( LD 50 ,  rat ,  oral )

As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

1-Chlorhexane is a chemical compound of chlorine from the group of aliphatic , unsaturated halogenated hydrocarbons .

Extraction and presentation

1-Chlorhexane can be obtained by reacting hexyl alcohol with hydrochloric acid or thionyl chloride .

properties

1-chlorohexane is a colorless liquid with an aromatic odor that is very sparingly soluble in water.

use

1-Fluorohexane can be obtained by reacting 1-chlorohexane with potassium fluoride in ethylene glycol , and 2-phenylhexane by reacting with benzene and aluminum trichloride .

safety instructions

The vapors of 1-chlorohexane can form an explosive mixture with air ( flash point 26 ° C, ignition temperature 204 ° C).

Individual evidence

  1. ↑ a b c d e f g h i j k Entry on 1-chlorohexane in the GESTIS substance database of the IFA , accessed on January 8, 2020(JavaScript required) .
  2. ↑ David R. Lide: CRC Handbook of Chemistry and Physics A Ready-reference Book of Chemical and Physical Data . CRC Press, 1995, ISBN 978-0-8493-0595-5 , pp. 112 ( limited preview in Google Book search).
  3. ↑ Data sheet 1-chlorohexane, 99% from Sigma-Aldrich , accessed on October 28, 2018 ( PDF ).
  4. ↑ Data sheet 1-chlorohexane (PDF) from Merck , accessed on October 28, 2018.
  5. ^ H. Altenburg, I. Bang, K. Bartelt, Fr. Baum, C. Brahm, W. Cramer, K. Dieterich, R. Ditmar, M. Dohrn, H. Einbeck, H. Euler, ES Faust, C. Funk, O. v. Fürth, O. Gerngroß: Biochemisches Handlexikon 1st volume, 1st half carbon, hydrocarbons, alcohols of the aliphatic series, phenols . Springer-Verlag, 2013, ISBN 978-3-642-90817-0 , pp. 95 ( limited preview in Google Book search).
  6. ↑ VK Ahluwalia, R. Aggarwal, VK Ahluwalia: Comprehensive Practical Organic Chemistry: Preparations And Quantitative Analysis . 2000, ISBN 81-7371-475-4 , pp. 16 ( limited preview in Google Book search).
  7. ^ Houben-Weyl Methods of Organic Chemistry Vol. V / 3, 4th Edition Fluorine and Chlorine Compounds . Georg Thieme Verlag, 2014, ISBN 3-13-179994-3 , p. 153 ( limited preview in Google Book search).
  8. ^ Marye Anne Fox, James K. Whitesell: Organic Chemistry . Jones & Bartlett Learning, 2004, ISBN 978-0-7637-2197-8 , pp. 530 ( limited preview in Google Book search).