N , N -diethylhydroxylamine

Structural formula
General
Surname	N , N -diethylhydroxylamine
other names	Diethyl hydroxylamine; N -ethyl- N -hydroxyethanamin; DEHA;
Molecular formula	C 4 H 11 NO
Brief description	colorless liquid with an amine-like odor
External identifiers / databases
EC number	223-055-4
ECHA InfoCard	100.020.960
PubChem	19463
ChemSpider	18340
Wikidata	Q3334148
properties
Molar mass	89.14 g mol −1
Physical state	liquid
density	0.87 g cm −3
Melting point	-25 ° C
boiling point	125-130 ° C
Vapor pressure	33 hPa (20 ° C)
solubility	soluble in water
Refractive index	1.420 (20 ° C)
safety instructions
H and P phrases	H: 226-312-332-335-411
	P: 210-261-280-332 + 313-337 + 313-312-403 + 233
Toxicological data	2190 mg kg −1 ( LD 50 , rat , oral ) ; 1300 mg kg −1 ( LD 50 , rabbit , transdermal ) ;
	As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

N , N -diethylhydroxylamine is a chemical compound from the group of hydroxylamine derivatives .

Extraction and presentation

N , N -Diethylhydroxylamin can be prepared by reaction of diethyl amine with hydrogen peroxide in tert -butyl alcohol and a titanium silicate - catalyst are recovered.

properties

N , N -diethylhydroxylamine is a volatile, colorless liquid with an amine-like odor, which is soluble in water.

use

N , N -diethylhydroxylamine is used as a photographic developer, antioxidant , corrosion inhibitor and as a reaction stopper in synthetic rubber production. It can also be used as a ligand in the preparation of unsymmetrical oxadiazoline and / or imine platinum complexes. It can also be used in the synthesis of organometallic clusters from mixed hydrazide / hydroxylamide clusters of zinc .

safety instructions

The vapors of N , N -diethylhydroxylamine can form an explosive mixture with air ( flash point 45 ° C).

Individual evidence

↑ ^a ^b ^c ^d ^e ^f ^g ^h ⁱ ^j ^k Entry on N, N-diethylhydroxylamine in the GESTIS substance database of the IFA , accessed on January 31, 2019(JavaScript required) .
↑ ^a ^b Data sheet N, N-Diethylhydroxylamine, ≥98% from Sigma-Aldrich , accessed on February 1, 2019 ( PDF ).
↑ ^a ^b Data sheet N, N-diethylhydroxylamine for synthesis (PDF) from Merck , accessed on February 1, 2019.
↑ EPO - T 0607/95 (Production of hydroxylamine / ENICHEM) of December 21 , 1999 , accessed on February 1, 2019.

↑ Entry on N, N-diethylhydroxylamine in the Hazardous Substances Data Bank , accessed on February 1, 2019.

↑ Michael Ash: Handbook of Preservatives . Synapse Info Resources, 2004, ISBN 978-1-890595-66-1 , pp. 362 ( limited preview in Google Book search).

[GESTIS-1] ↑ ^a ^b ^c ^d ^e ^f ^g ^h ⁱ ^j ^k Entry on N, N-diethylhydroxylamine in the GESTIS substance database of the IFA , accessed on January 31, 2019(JavaScript required) .

[Sigma-2] Data sheet N, N-Diethylhydroxylamine, ≥98% from Sigma-Aldrich , accessed on February 1, 2019 ( PDF ).

[Merck-3] Data sheet N, N-diethylhydroxylamine for synthesis (PDF) from Merck , accessed on February 1, 2019.

[epo.org-4] EPO - T 0607/95 (Production of hydroxylamine / ENICHEM) of December 21 , 1999 , accessed on February 1, 2019.

[HSDB-5] Entry on N, N-diethylhydroxylamine in the Hazardous Substances Data Bank , accessed on February 1, 2019.

[Michael_Ash-6] Michael Ash: Handbook of Preservatives . Synapse Info Resources, 2004, ISBN 978-1-890595-66-1 , pp. 362 ( limited preview in Google Book search).