Methyl propionate

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Structural formula
Structure of methyl propionate
General
Surname Methyl propionate
other names
  • Methyl propanoate
  • Methyl propionate
Molecular formula C 4 H 8 O 2
Brief description

colorless liquid with a fruity odor

External identifiers / databases
CAS number 554-12-1
EC number 209-060-4
ECHA InfoCard 100.008.238
PubChem 11124
Wikidata Q418391
properties
Molar mass 88.11 g mol −1
Physical state

liquid

density

0.91 g cm −3

Melting point

−88 ° C

boiling point

80 ° C

Vapor pressure

122 hPa (25 ° C)

solubility
  • heavy in water (5 g l −1 at 20 ° C)
  • Soluble in most organic solvents
Refractive index

1.377

safety instructions
GHS hazard labeling from  Regulation (EC) No. 1272/2008 (CLP) , expanded if necessary
02 - Highly / extremely flammable 07 - Warning

danger

H and P phrases H: 225-332
P: 210-240-304 + 340
Toxicological data
As far as possible and customary, SI units are used. Unless otherwise noted, the data given apply to standard conditions . Refractive index: Na-D line , 20 ° C

Propionic acid methyl ester is the methyl ester of propionic acid .

Extraction and presentation

Propionic acid methyl ester can be prepared by esterification of propionic acid with methanol are produced.

Industrial methyl propionate is produced by reacting ethene with carbon monoxide and methanol in the presence of nickel tetracarbonyl at 160 - 200 ° C and 50 bar.

use

Methyl propionate is used as a solvent for lacquers and as a base for further syntheses (e.g. that of methyl methacrylate , the monomer in acrylic glass ). Due to its rum-like smell and taste , it is also used as a fragrance and aroma .

Individual evidence

  1. a b c d e f g h i j k Entry on methyl propionate in the GESTIS substance database of the IFA , accessed on February 1, 2016(JavaScript required) .
  2. ^ Richard J. Lewis, Sr .: Hawley's Condensed Chemical Dictionary . 15th edition. Wiley-Interscience, 2007, ISBN 978-0-471-76865-4 (English).
  3. Entry on methyl propionate in the Classification and Labeling Inventory of the European Chemicals Agency (ECHA), accessed on February 1, 2016. Manufacturers or distributors can expand the harmonized classification and labeling .
  4. a b Ulf-Rainer Samel, Walter Kohler, Armin Otto Gamer and Ullrich Keuser: Propionic Acid and Derivatives . In: Ullmann's Encyclopedia of Industrial Chemistry . 2000, ISBN 978-3-527-30673-2 , doi : 10.1002 / 14356007.a22_223.pub2 .