Neustädtelit

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Neustädtelit
Neustädtelite.jpg
Brownish Neustädtelite crystals from the type locality Grube "Güldener Falk" near Neustädtel (Schneeberg) , Saxony
General and classification
other names

IMA 1998-016

chemical formula Bi 2 Fe 3+ Fe 3+ O 2 (OH) 2 (AsO 4 ) 2
Mineral class
(and possibly department)
Phosphates, arsenates and vanadates
System no. to Strunz
and to Dana
8.BK.10 ( 8th edition : VII / B.37)
04.41.09.02
Crystallographic Data
Crystal system triclinic
Crystal class ; symbol triclinic pinacoidal; 1
Space group P 1 (No. 2)Template: room group / 2
Lattice parameters a  = 4.556 (1)  Å ; b  = 6.153 (2) Å; c  = 8.984 (2) Å
α  = 95.43 (2) °; β  = 99.22 (2) °; γ  = 92.95 (3) °
Formula units Z  = 1/2
Physical Properties
Mohs hardness 4.5
Density (g / cm 3 ) calculated: 5.81
Cleavage good after {001}
Break ; Tenacity clamshell; brittle
colour brown, brown-red, black
Line color light brown
transparency transparent to translucent
shine Diamond luster
Crystal optics
Refractive indices n α  = 2.020
n β  = 2.080
n γ  = 2.120
Birefringence δ = 0.100
Optical character biaxial negative
Axis angle 2V = 65 (5) °
Pleochroism strong: X = brown, Y = yellow, Z = light yellow

Neustädtelit is a very rarely occurring mineral from the mineral class of " phosphates , arsenates and vanadates ". It crystallizes in the triclinic crystal system with the chemical composition Bi 2 Fe 3+ Fe 3+ O 2 (OH) 2 (AsO 4 ) 2 , so it is a bismuth - iron arsenate with additional hydroxide ions .

Neustädtelite only develops small, tabular crystals with a tabular habit up to about 0.2 millimeters in diameter of brown, brown-red or black color with light brown streak color . The surfaces of the transparent to translucent crystal surfaces show a diamond-like sheen .

Etymology and history

Neustädtelite was first discovered together with cobaltneustädtelite on the heaps of the "Güldener Falk" mine near Neustädtel (Schneeberg) in the Saxon Ore Mountains and described in 2002 by Werner Krause, Heinz-Jürgen Bernhardt, Catherine McCammon and Herta Effenberger, who named the mineral after its type of locality .

The type material of the mineral is kept in the collection of the State Museum for Mineralogy and Geology Dresden in Germany (catalog nos. 18328 and 18329).

classification

Already in the now outdated, but still common 8th edition of the mineral classification according to Strunz , Neustädtelite belonged to the mineral class of "phosphates, arsenates and vanadates" and there to the department of "anhydrous phosphates, with foreign anions F, Cl, O, OH", where he together with Brendelit , Cobaltneustädtelit , Medenbachit and Paulkellerit the unnamed group VII / B.37 formed.

The 9th edition of Strunz's mineral systematics , which has been in effect since 2001 and is used by the International Mineralogical Association (IMA), also assigns Neustädtelite to the category of “phosphates etc. with additional anions; without H 2 O “. However, this is further subdivided according to the relative size of the cations involved and the molar ratio of the additional anions (OH etc.) to the phosphate, arsenate or vanadate complex (RO 4 ), so that the mineral can be classified in the sub-section “With medium-sized and large cations; (OH etc.): RO 4  = 2: 1, 2.5: 1 “can be found, where only together with cobalt neustädtelite and medenbachite the“ medenbachite group ”with the system no. 8.BK.10 forms.

The systematics of minerals according to Dana , which is mainly used in the English-speaking world , assigns Neustädtelite to the class of "phosphates, arsenates and vanadates" and there to the category of "anhydrous phosphates etc., with hydroxyl or halogen". Here it is also together with medenbachite and cobalt neustädtelite in the " medenbachite group " with the system no. 04/41/09 within the subsection “Anhydrous phosphates etc., with hydroxyl or halogen with (AB) 5 (XO 4 ) 2 Z q ”.

Crystal structure

Neustädtelite crystallizes triclinically in the space group P 1 (space group no. 2) with the lattice parameters a  = 4.556 (1)  Å ; b  = 6.153 (2) Å; c  = 8.984 (2) Å; α = 95.43 (2) °; β = 99.22 (2) ° and γ = 92.95 (3) ° as well as ½ formula unit per unit cell . Template: room group / 2

Education and Locations

The samples, which contain Neustädtelite and Cobaltneustädtelite, consist mainly of quartz , where the two minerals crystallize in small cavities. The accompanying minerals include goethite , limonite and prizingerite , and rarely also bismuthite , mixite and zeunerite .

As a rare mineral formation, Neustädtelite could only be detected at a few sites, whereby so far (as of 2013) fewer than 20 sites are known.

In addition to its type locality “Güldener Falk” mine, the mineral was also found on several mine dumps around Neustädtel and Schneeberg (Erzgebirge) such as the “Adam Heber”, “Junge Kalbe” and “Peter and Paul” mines (today Marx-Semler-Stolln ) as well as found near Tirpersdorf (Vogtlandkreis) and the "Father Abraham" mine near Lauta in Saxony. Furthermore, Neustädtelite has so far been found in several pits near Lichtenberg (Upper Franconia) near Bad Steben in Bavaria (as of 2013).

See also

literature

  • Werner Krause, Heinz-Jürgen Bernhardt, Catherine McCammon, Herta Effenberger: Neustädtelite and cobaltneustädtelite, the Fe 3+ - and Co 2+ -analogues of medenbachite . In: American Mineralogist . tape 87 , 2002, pp. 726-738 ( rruff.info [PDF; 388 kB ; accessed on May 10, 2018]).

Web links

Commons : Neustädtelite  - Collection of images, videos and audio files

Individual evidence

  1. a b c d e f g h i Werner Krause, Heinz-Jürgen Bernhardt, Catherine McCammon, Herta Effenberger: Neustädtelite and cobaltneustädtelite, the Fe 3+ - and Co 2+ -analogues of medenbachite . In: American Mineralogist . tape 87 , 2002, pp. 726-738 ( rruff.info [PDF; 388 kB ; accessed on May 10, 2018]).
  2. a b Mindat - Neustädtelit
  3. Mindat - Number of localities for Neustädtelite
  4. Find location list for Neustädtelite at the Mineralienatlas and at Mindat