List of restricted substances - Annex XVII of the REACH regulation
This list of restricted substances contains the dangerous substances listed in Annex XVII of the REACH Regulation , for which the manufacture, placing on the market or use are restricted or prohibited. As of August 12, 2020, the following substances / groups of substances were listed in Annex XVII.
| entry | material | CAS number | EC number | Constraint condition |
|---|---|---|---|---|
| 1 | polychlorinated terphenyls (PCT) | Placing on the market as a substance as substances, in mixtures, with more than 0.005% by weight. | ||
| 2 | Chloroethene (vinyl chloride) | 75-01-4 | 200-831-0 | Used as a propellant for aerosols. |
| 3 | Liquid substances / mixtures of hazard classes 2.1 to 2.4, 2.6, 2.7, 2.8 (type A and B), 2.9, 2.10, 2.12, 2.13 (cat 1 and 2), 2.14 (cat 1 and 2), 2.15 (type A to F ), 3.1 to 3.10, 4.1 5.1 according to Regulation (EC) No. 1272/2008 (CLP) | Various uses and placing on the market e.g. B if marked with H304 . | ||
| 4th | Tris (2,3-dibromopropyl) phosphate (TDPP) | 126-72-7 | Use in textiles with skin contact and their placing on the market. | |
| 5 | benzene | 71-43-2 | 200-753-7 | Placing on the market as a substance or in mixtures with ≥ 0.1% by weight (with the exception of fuels and natural gas), use in toys |
| 6th | Asbestos fibers | Prohibition of the manufacture, placing on the market and use of the fibers and products made from them. | ||
| a) crocidolite | 12001-28-4 | |||
| b) amosite | 12172-73-5 | |||
| c) anthophyllite | 77536-67-5 | |||
| d) actinolite | 77536-66-4 | |||
| e) tremolite | 77536-68-6 | |||
| f) chrysotile | 12001-29-5 132207-32-0 |
|||
| 7th | Tris (aziridinyl) phosphine oxide | 545-55-1 | 208-892-5 | Use in textiles with skin contact and their placing on the market. |
| 8th | Polybromobiphenyls, polybrominated biphenyls (PBB) | 59536-65-1 | ||
| 9 | a.) Panamarind powder | 68990-67-0 | 273-620-4 | Use in joke articles , such as sneezing powder and stink bombs |
| b.) Powder from the root of the green hellebore | ||||
| c.) Powder from the root of the white hellebore | ||||
| d.) Benzidine and its derivatives | 92-87-5 | 202-199-1 | ||
| e.) o-nitrobenzaldehyde | 552-89-6 | 209-025-3 | ||
| Wood dust | ||||
| 10 | a) ammonium sulfide | 12135-76-1 | 235-223-4 | Use in joke articles, such as sneezing powder and stink bombs |
| b) ammonium hydrogen sulfide | 2124-99-1 | 235-184-3 | ||
| c) ammonium polysulphide | 9080-17-5 | 232-989-1 | ||
| 11 | Volatile esters of bromoacetic acid : | Use in joke articles, such as sneezing powder and stink bombs | ||
| a) methyl bromoacetate | 96-32-2 | 202-499-2 | ||
| b) ethyl bromoacetate | 105-36-2 | 203-290-9 | ||
| c) propyl bromoacetate | 35223-80-4 | |||
| d) butyl bromoacetate | 18991-98-5 | 242-729-9 | ||
| 12 | 2-naphthylamine and its salts | 91-59-8 | 202-080-4 | Use or placing on the market as a substance or in mixtures with> 0.1% by weight. |
| 13 | Benzidine and its salts | 92-87-5 | 202-199-1 | Use or placing on the market as a substance or in mixtures with> 0.1% by weight. |
| 14th | 4-nitrobiphenyl | 92-93-3 | 202-204-7 | Use or placing on the market as a substance or in mixtures with> 0.1% by weight. |
| 15th | 4-aminobiphenyl , (xenylamine) and its salts | 92-67-1 | 202-177-1 | Use or placing on the market as a substance or in mixtures with> 0.1% by weight. |
| 16 | Lead carbonates: | Use and placing on the market in colors. | ||
| a) Lead carbonate PbCO 3 | 598-63-0 | 209-943-4 | ||
| b) White lead 2PbCO 3 -Pb (OH) 2 | 1319-46-6 | 215-290-6 | ||
| 17th | Lead sulfate : | Use and placing on the market in colors. | ||
| a) PbSO 4 | 7446-14-2 | 231-198-9 | ||
| b) Pb x SO 4 | 15739-80-7 | 239-831-0 | ||
| 18th | Mercury compounds | Use and marketing against microorganisms, plants or animals, as wood protection , for impregnation , for water treatment . | ||
| 18a | mercury | Placing on the market in clinical thermometers and measuring instruments . | ||
| 19th | Arsenic compounds | Use and marketing against microorganisms, plants or animals, as wood protection, for water treatment. | ||
| 20th | Organotin compounds | Use and placing on the market as biocides , for water treatment. | ||
| 21st | Di-μ-oxo-di-n-butylstanniohydroxyborane, dibutyltin hydrogen borate (DBB) | 75113-37-0 | 401-040-5 | Placing on the market as a substance or in mixtures with ≥ 0.1% by weight. |
| 22nd | Pentachlorophenol and its salts and esters | 87-86-5 | 201-778-6 | Placing on the market as a substance or in mixtures with ≥ 0.1% by weight. |
| 23 | Cadmium and its compounds | 7440-43-9 | 231-152-8 | Use in plastics such as PVC and placing on the market, use in hard solders . |
| 24 | Monomethyl-tetrachlorodiphenylmethane (trade name Ugilec 141) | 76253-60-6 | Use and placing on the market as a substance or in mixtures. | |
| 25th | Monomethyl – dichlorodiphenylmethane (trade name Ugilec 121) | Use and placing on the market as a substance or in mixtures. | ||
| 26th | Monomethyl-dibromodiphenylmethane, bromobenzylbromotoluene, mixture of isomers (DBBT) | 99688-47-8 | Use and placing on the market as a substance or in mixtures. | |
| 27 | Nickel and its compounds | 7440-02-0 | 231-111-4 | Use in products with direct skin contact. |
| 28 | Carcinogenic substances of category 1A or 1B according to Annex VI Part 3 of Regulation (EC) No. 1272/2008 (CLP) . | Use and placing on the market as a substance, constituents of other substances or in mixtures that are intended for sale to the general public if the specific individual concentration is exceeded. Marking For commercial users only . | ||
| 29 | mutagenic substances of category 1A or 1B according to Annex VI Part 3 of Regulation (EC) No. 1272/2008 (CLP) . | Use and placing on the market as a substance, constituents of other substances or in mixtures that are intended for sale to the general public if the specific individual concentration is exceeded. Marking For commercial users only . | ||
| 30th | Teratogenic substances of category 1A or 1B according to Annex VI Part 3 of Regulation (EC) No. 1272/2008 (CLP) . | Use and placing on the market as a substance, constituents of other substances or in mixtures that are intended for sale to the general public if the specific individual concentration is exceeded. Marking For commercial users only . | ||
| 31 | a) Creosote washing oil | 8001-58-9 | 232-287-5 | Use and placing on the market as a substance, components of other substances or in mixtures for wood treatment |
| b) creosote oil, washing oil | 61789-28-4 | 263-047-8 | ||
| c) Distillates (coal tar), naphthalene oils; Naphthalene oil | 84650-04-4 | 283-484-8 | ||
| d) creosote oil, acenaphthene fraction; Washing oil | 90640-84-9 | 292-605-3 | ||
| e) higher boiling distillates (coal tar); heavy anthracene oil | 65996-91-0 | 266-026-1 | ||
| f) anthracene oil | 90640-80-5 | 292-602-7 | ||
| g) tar acids, coal, crude oil; Crude phenols | 65996-85-2 | 266-019-3 | ||
| h) creosote, wood | 8021-39-4 | 232-419-1 | ||
| i) Low temperature coal tar alkaline, extract residues (coal) | 122384-78-5 | 310-191-5 | ||
| 32 | chloroform | 67-66-3 | 200-663-8 | Use and placing on the market for the general public as a substance, constituents of other substances or in mixtures with ≥ 0.1% by weight. |
| 33 | not applicable (originally carbon tetrachloride ) | |||
| 34 | 1,1,2-trichloroethane | 79-00-5 | 201-166-9 | Use and placing on the market for the general public as a substance, constituents of other substances or in mixtures with ≥ 0.1% by weight. |
| 35 | 1,1,2,2-tetrachloroethane | 79-34-5 | 201-197-8 | Use and placing on the market for the general public as a substance, constituents of other substances or in mixtures with ≥ 0.1% by weight. |
| 36 | 1,1,1,2-tetrachloroethane | 630-20-6 | Use and placing on the market for the general public as a substance, constituents of other substances or in mixtures with ≥ 0.1% by weight. | |
| 37 | Pentachloroethane | 76-01-7 | 200-925-1 | Use and placing on the market for the general public as a substance, constituents of other substances or in mixtures with ≥ 0.1% by weight. |
| 38 | 1,1-dichloroethene | 75-35-4 | 200-864-0 | Use and placing on the market for the general public as a substance, constituents of other substances or in mixtures with ≥ 0.1% by weight. |
| 39 | not applicable (originally 1,1,1-trichloroethane ) | |||
| 40 | Flammable gases (categories 1, 2), flammable liquids (categories 1, 2, 3), flammable solids (categories 1, 2), substances / mixtures that develop flammable gases with water (categories 1, 2, 3), pyrophoric liquids (Category 1), pyrophoric solids (Category 1) | Use as a substance or in mixtures for aerosol dispensers for entertainment and decoration purposes. Marking For commercial users only . | ||
| 41 | Hexachloroethane | 67-72-1 | 200-666-4 | Use or placing on the market as a substance or in mixtures for the production or processing of non-ferrous metals. |
| 42 | not applicable (originally chloroalkanes C 10 -C 13 , short-chain chlorinated paraffins , SCCP ) | |||
| 43 | Azo dyes , if they can release an aromatic amine listed in Appendix 8 through reductive cleavage, as well as azo dyes listed in Appendix 9. | Use and placing on the market for dyeing textile or leather products which may come into direct contact with human skin or the oral cavity for a longer period of time. | ||
| 44 | not applicable (originally pentabromodiphenyl ether C 12 H 5 Br 5 O) | |||
| 45 | Octabromodiphenyl ether | Use and placing on the market as a substance, constituents of other substances or in mixtures with ≥ 0.1% by weight. | ||
| 46 | a.) Nonylphenol | 25154-52-3 | 246-672-0 | Use and placing on the market as a substance, components of other substances or in mixtures with ≥ 0.1% by weight for industrial and commercial cleaning, household cleaning, textile and leather processing, emulsification in milking fat, production of cellulose, cosmetic and body care products, auxiliary in Pesticides. |
| b.) Nonylphenol ethoxylates | ||||
| 46a | Nonylphenol ethoxylates | Use in textile products | ||
| 47 | Chromium (VI) compounds | Placing on the market cement and cement products with a chromium (VI) content> 2 mg / kg. | ||
| 48 | toluene | 108-88-3 | 203-625-9 | Use and placing on the market as a substance or in mixtures in concentrations of ≥ 0.1% by weight in adhesives and spray paint cans for distribution to the general public. |
| 49 | Trichlorobenzene | 120-82-1 | 204-428-0 | Use and placing on the market as a substance or in mixtures in a concentration of ≥ 0.1% by weight |
| 50 | Polycyclic aromatic hydrocarbons | Use and placing on the market for the manufacture of tires or tire components and products made of plastic in contact with the skin. | ||
| a) Benzo [ a ] pyrene (BaP) | 50-32-8 | |||
| b) Benzo [ e ] pyrene (BeP) | 192-97-2 | |||
| c) Benzo [ a ] anthracene (BaA) | 56-55-3 | |||
| d) Chrysene (CHR) | 218-01-9 | |||
| e) Benzo [ b ] fluoranthene (BbFA) | 205-99-2 | |||
| f) Benzo [ j ] fluoranthene (BjFA) | 205-82-3 | |||
| g) Benzo [ k ] fluoranthene (BkFA) | 207-08-9 | |||
| h) Dibenzo [ a, h ] anthracene (DBAhA) | 53-70-3 | |||
| 51 | Bis (2-ethylhexyl) phthalate (DEHP) | 117-81-7 | 204-211-0 | Use as substances or in mixtures individually or in a combination if the concentration in products corresponds to ≥ 0.1% by weight. |
| Dibutyl phthalate (DBP) | 84-74-2 | 201-557-4 | ||
| Benzyl butyl phthalate (BBP) | 85-68-7 | 201-622-7 | ||
| Diisobutyl phthalate (DIBP) | 84-69-5 | 201-553-2 | ||
| 52 | The following phthalates | Use or placing on the market as substances or in mixtures in concentrations of> 0.1% by weight in toys and baby articles that can be put into the mouth by children. | ||
| a) disononyl phthalate (DINP) | 28553-12-0 68515-48-0 |
249-079-5 271-090-9 |
||
| b) diisodecyl phthalate (DIDP) | 26761-40-0 68515-49-1 |
247-977-1 271-091-4 |
||
| Di- n -octyl phthalate (DNOP) | 117-84-0 | 204-214-7 | ||
| 53 | not applicable (originally perfluorooctanesulfonate (PFOS) C 8 F 17 SO 2 X, with X = OH, metal salts, halides, amides and other derivatives including polymers) | |||
| 54 | Diethylene glycol monomethyl ether (DEGME) | 111-77-3 | 203-906-6 | Placing on the market in paints, paint strippers, cleaning agents, self-shining emulsions or floor sealants for the general public in a concentration of ≥ 0.1% by weight. |
| 55 | Butyldiglycol (DEGBE) | 112-34-5 | 203-961-6 | Placing on the market to the general public in spray paints or cleaning sprays in aerosol dispensers in a concentration of ≥ 3% by weight. |
| 56 | Methylenediphenyl diisocyanate (MDI) | 26447-40-5 | 247-714-0 | Placing on the general public in mixtures containing this substance in a concentration of ≥ 0.1% by weight under certain conditions. |
| a) 4,4'-methylenediphenyl diisocyanate | 101-68-8 | 202-966-0 | ||
| b) 2,4'-methylenediphenyl diisocyanate | 5873-54-1 | 227-534-9 | ||
| c) 2,2'-methylenediphenyl diisocyanate | 2536-05-2 | 19-799-4 | ||
| 57 | Cyclohexane | 110-82-7 | 203-806-2 | Placing on the market to the general public in neoprene- based contact adhesives in a concentration of ≥ 0.1% by weight in package sizes> 350 g. |
| 58 | Ammonium nitrate | 6484-52-2 | 229-347-8 | Placing on the market as a fertilizer with more than 16 or 28% by weight nitrogen. |
| 59 | Dichloromethane | 75-09-2 | 200-838-9 | Placing on the market in paint strippers containing dichloromethane (DCM) in a concentration of ≥ 0.1% by weight. |
| 60 | Acrylamide | 79-06-1 | Use and placing on the market as a substance or in mixtures in concentrations of ≥ 0.1% by weight for sealing applications (injection, grouting, grouting or potting). | |
| 61 | Dimethyl fumarate (DMF) | 624-49-7 | 210-849-0 | Use and placing on the market in articles or components thereof in a concentration of ≥ 0.1 mg / kg. |
| 62 | a) phenyl mercury acetate | 62-38-4 | 200-532-5 | Use and placing on the market as a substance or in mixtures with a mercury concentration ≥ 0.01% by weight. |
| b) phenyl mercury propionate | 103-27-5 | 203-094-3 | ||
| c) phenyl mercury 2-ethylhexanoate | 236-326-7 | 13302-00-6 | ||
| d) phenyl mercury octanoate | 13864-38-5 | |||
| e) phenyl mercury neodecanoate | 26545-49-3 | 247-783-7 | ||
| 63 | Lead and its compounds | 7439-92-1 | 231-100-4 | Use and placing on the market in jewelry with a lead content of ≥ 0.05% by weight. |
| 64 | 1,4-dichlorobenzene | 106-46-7 | 203-400-5 | Use and placing on the market as a substance or component of mixtures in air fresheners or deodorants in toilets, private households, offices or other publicly accessible indoor spaces with ≥ 1% by weight. |
| 65 | Inorganic ammonium salts | Use and placing on the market in cellulose insulation material mixtures / cellulose insulation material products if the emission of ammonia from these mixtures or products is ≥ 3 ppm (2.12 mg / m 3 ). | ||
| 66 | Bisphenol A. | 80-05-7 | 201-245-8 | Placing on the market in thermal paper in a concentration ≥ 0.02% by weight. |
| 67 | Bis (pentabromophenyl) ether (decabromodiphenyl ether, DecaBDE) | 1163-19-5 | 214-604-9 | Manufacture and placing on the market as a substance, component of another substance, mixture or article in a concentration of ≥ 0.1% by weight. |
| 68 | Perfluorooctanoic acid (PFOA), its salts and precursor compounds with a C 7 F 15 group | 335-67-1 | 206-397-9 | Manufacturing and placing on the market as a substance, component of another substance, mixture or article in a concentration of ≥ 25 ppb . |
| 69 | Methanol | 67-56-1 | 200-659-6 | Placing on the general public in windscreen washer fluids or windscreen antifreeze in a concentration ≥ 0.6% by weight. |
| 70 | Octamethylcyclotetrasiloxane (D 4 ) | 556-67-2 | 209-136-7 | Placing on the market in washable cosmetic products in a concentration of ≥ 0.1% by weight. |
| Decamethylcyclopentasiloxane (D 5 ) | 541-02-6 | 208-764-9 | ||
| 71 | 1-methyl-2-pyrrolidone (NMP) | 872-50-4 | 212-828-1 | Manufacture, use and placing on the market as a substance or in mixtures in concentrations of ≥ 0.3%. |
| 72 | The substances listed in column 1 of the table in Appendix 12 | Placing on the market in clothing and accessories, footwear if the concentration is above the limit values in Appendix 12 after November 1, 2020. | ||
| 73 | (3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl) silanetriol its mono-, di- or tri- O- (alkyl) derivatives | Marketing to the general public in spray products (aerosol dispensers, pump sprays, trigger sprays for sealing or impregnating spray applications) in a total concentration of ≥ 2 ppb after January 2, 2021. | ||
| 74 | Diisocyanates (O = C = NRN = C = O, where R is an aliphatic or aromatic hydrocarbon unit of any length) | Industrial or commercial use as a substance, component in other substances or in mixtures in concentration individually and in combination of ≥ 0.1% by weight after February 24, 2022/24. August 2023. |
Notes (A):
- ↑ Summary of the restriction. For the exact wording, in particular restrictions and exceptions, please look up the relevant legal text.
- ↑ By Regulation (EC) no. 2037/2000 , the use was banned with few exceptions in the EU and in accordance with the Regulation (EC) no. 2037/2000 deleted from the Annex XVII.
- ↑ By Regulation (EC) no. 2037/2000 use in the EU was banned and in accordance with the Regulation (EC) no. 2037/2000 deleted from Annex XVII of the REACH Regulation.
- ↑ Through Regulation (EU) No. 519/2012 , SCCP were included in Annex I of Regulation (EC) No. 850/2004 , whereby production, placing on the market and use - apart from certain exceptions - are prohibited. Entry 42 in Annex XVII has therefore become superfluous and has been deleted from Annex XVII of the REACH Regulation by Regulation (EU) No. 126/2013 .
- ↑ Biphenyl-4-ylamine, benzidine, 4-chloro- o -toluidine , 2-naphthylamine, o -aminoazotoluene, 5-nitro- o -toluidine , 4-chloroaniline , 4-methoxy- m -phenylenediamine , 4,4′- methylenedianiline , 3,3'-dichlorobenzidine , 3,3'-dimethoxybenzidine , 3,3'-dimethylbenzidine , 4,4'-methylenedi o -toluidin , p -Kresidin , 4,4'-methylene-bis (2-chloroaniline ) , 4,4'-oxydianiline , 4,4'-thiodianiline , o -toluidine , 4-methyl- m -phenylenediamine , 2,4,5-trimethylaniline , o-anisidine , 4-aminoazobenzene .
- ↑ By Regulation (EU) no. 757/2010 pentabromodiphenylether were in Annex I to Regulation (EC) no. 850/2004 added, are making the manufacture and supply prohibited. Entry 44 in Annex XVII has therefore become superfluous and has been deleted from Annex XVII of the REACH Regulation by Regulation (EU) No. 207/2011 .
- ↑ Through Regulation (EU) No. 757/2010 PFOS were included in Annex I of Regulation (EC) No. 850/2004 , which prohibits production and marketing. Entry 53 in Annex XVII has therefore become superfluous and has been deleted from Annex XVII of the REACH Regulation by Regulation (EU) No. 207/2011 . The exceptions in Annex XVII of the REACH regulation have been included in Annex I of Regulation (EC) No. 850/2004.
- ↑ Cadmium and cadmium compounds, chromium (VI) compounds, arsenic compounds, lead and lead compounds, benzene, benz [ a ] anthracene, benz [ e ] acephenanthrylene, benzo [ a ] pyrene, benzo [ def ] chrysen, benzo [ e ] pyrene, Benzo [ j ] fluoranthene, benzo [ k ] fluoranthene, chrysene, dibenz [ a, h ] anthracene, α, α, α, 4-tetrachlorotoluene , α, α, α-trichlorotoluene , p -chlorotoluene (benzyl chloride), formaldehyde , di -C 6-8 -branched alkyl esters of 1,2-benzenedicarboxylic acid (C 7 -rich), bis (2-methoxyethyl) phthalate , diisopentyl phthalate , di- n -pentyl phthalate (DPP), di- n -hexyl phthalate (DnHP), N -Methyl-2-pyrrolidone (1-methyl-2-pyrrolidone, NMP), N , N -dimethylacetamide (DMAC), 1,4,5,8-tetraaminoanthraquinone (CI Disperse Blue 1), 4,4 ′ - (4 -Iminocyclohexa-2,5-dienylidenemethylene) dianiline hydrochloride ( parafuchsin hydrochloride , CI Basic Red 9), [4- [4,4'-bis (dimethylamino) benzhydrylidene] cyclohexa-2,5-dien-1-ylidene] dimethylammonium chloride (CI Basic Violet 3) with ≥ 0.1% Michler's ketone , 4-chloro- o -toluidinium chloride , 2-naphthylammonium acetate , 4-methoxy- m -phenylenediammonium sulfate (2,4-diaminoanisole sulfate), 2,4,5-trimethylaniline hydrochloride , quinoline
- ↑ Adopted by Regulation (EU) 2019/957 , entry into force on August 1, 2019.
- ↑ Adopted by Regulation (EU) 2020/1149 , entry into force on 23 August 2020.
Individual evidence
- ↑ ECHA: List of restricted substances - Annex XVII of the REACH regulation , accessed on August 12, 2020.